Department of Materials Science, University of Milano-Bicocca, U5 Via Cozzi 55, 20125, Milan, Italy.
Istituto di Chimica Dei Composti OrganoMetallici (ICCOM), Consiglio Nazionale Delle Ricerche (CNR), Via Madonna Del Piano 10, 50019, Sesto Fiorentino, Firenze, Italy.
ChemSusChem. 2022 Jan 21;15(2):e202102351. doi: 10.1002/cssc.202102351. Epub 2021 Dec 9.
A novel route for the valorization of waste into valuable products was developed. Surgical masks commonly used for COVID 19 protection by stopping aerosol and droplets have been widely used, and their disposal is critical and often not properly pursued. This work intended to transform surgical masks into platinum group metal-free electrocatalysts for oxygen reduction reaction (ORR) and hydrogen evolution reaction (HER) as well as into crude oil. Surgical masks were subjected to controlled-temperature and -atmosphere pyrolysis, and the produced char was then converted into electrocatalysts by functionalizing it with metal phthalocyanine of interest. The electrocatalytic performance characterization towards ORR and HER was carried out highlighting promising activity. At different temperatures, condensable oil fractions were acquired and thoroughly analyzed. Transformation of waste surgical masks into electrocatalysts and crude oil can open new routes for the conversion of waste into valuable products within the core of the circular economy.
开发了一种将废物转化为有价值产品的新途径。用于阻止气溶胶和飞沫的 COVID-19 防护的外科口罩已被广泛使用,但其处理至关重要,但往往没有得到妥善处理。本工作旨在将外科口罩转化为无贵金属的氧还原反应 (ORR) 和析氢反应 (HER) 电催化剂,以及转化为原油。外科口罩经过控温和控气氛热解,然后通过用感兴趣的金属酞菁官能化来将产生的炭转化为电催化剂。对 ORR 和 HER 的电催化性能进行了表征,突出了其有前途的活性。在不同温度下,获得了可冷凝油馏分并进行了详细分析。将废弃的外科口罩转化为电催化剂和原油,可以为废物转化为循环经济核心内有价值产品开辟新途径。