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通过热化学途径将新冠疫情期间的口罩废弃物转化为能源:共投喂食物废弃物的影响。

COVID-19 mask waste to energy via thermochemical pathway: Effect of Co-Feeding food waste.

作者信息

Park Chanyeong, Choi Heeyoung, Andrew Lin Kun-Yi, Kwon Eilhann E, Lee Jechan

机构信息

Department of Energy Systems Research, Ajou University, 206 World Cup-ro, Suwon, 16499, Republic of Korea.

Department of Environmental and Safety Engineering, Ajou University, 206 World Cup-ro, Suwon, 16499, Republic of Korea.

出版信息

Energy (Oxf). 2021 Sep 1;230:120876. doi: 10.1016/j.energy.2021.120876. Epub 2021 May 7.

Abstract

In this study, co-pyrolysis of single-use face mask (for the protection against COVID-19) and food waste was investigated for the purpose of energy and resource valorization of the waste materials. To this end, disposable face mask (a piece of personal protective equipment) was pyrolyzed to produce fuel-range chemicals. The pyrolytic gas evolved from the pyrolysis of the single-use face mask consisted primarily of non-condensable permanent hydrocarbons such as CH, CH, CH, CH, and CH. An increase in pyrolysis temperature enhanced the non-condensable hydrocarbon yields. The pyrolytic gas had a HHV of >40 MJ kg. In addition, hydrocarbons with wider carbon number ranges (e.g., gasoline-, jet fuel-, diesel-, and motor oil-range hydrocarbons) were produced in the pyrolysis of the disposable face mask. The yields of the gasoline-, jet fuel-, and diesel-range hydrocarbons obtained from the single-use mask were highest at 973 K. The pyrolysis of the single-use face mask yielded 14.7 wt% gasoline-, 18.4 wt% jet fuel-, 34.1 wt% diesel-, and 18.1 wt% motor oil-range hydrocarbons. No solid char was produced via the pyrolysis of the disposable face mask. The addition of food waste to the pyrolysis feedstock led to the formation of char, but the presence of the single-use face mask did not affect the properties and energy content of the char. More H and less hydrocarbons were produced by co-feeding food waste in the pyrolysis of the disposable face mask. The results of this study can contribute to thermochemical management and utilization of everyday waste as a source of energy.

摘要

在本研究中,为了实现废弃材料的能源化和资源化,对一次性口罩(用于预防新冠病毒)与食物垃圾的共热解进行了研究。为此,将一次性口罩(一种个人防护装备)进行热解以生产燃料级化学品。一次性口罩热解产生的热解气主要由不可冷凝的永久性碳氢化合物组成,如CH、CH、CH、CH和CH。热解温度的升高提高了不可冷凝碳氢化合物的产率。该热解气的高热值>40 MJ kg。此外,在一次性口罩的热解过程中还产生了碳数范围更广的碳氢化合物(如汽油级、喷气燃料级、柴油级和机油级碳氢化合物)。从一次性口罩中获得的汽油级、喷气燃料级和柴油级碳氢化合物的产率在973 K时最高。一次性口罩的热解产生了14.7 wt%的汽油级、18.4 wt%的喷气燃料级、34.1 wt%的柴油级和18.1 wt%的机油级碳氢化合物。一次性口罩热解未产生固体焦炭。在热解原料中添加食物垃圾会导致焦炭的形成,但一次性口罩的存在并不影响焦炭的性质和能量含量。在一次性口罩热解过程中共同加入食物垃圾会产生更多的氢气和更少的碳氢化合物。本研究结果有助于对日常废物进行热化学管理和作为能源加以利用。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/71a1/8103777/7bc0cff39754/ga1_lrg.jpg

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