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MXenes 作为新兴纳米材料在水净化和环境修复中的应用。

MXenes as emerging nanomaterials in water purification and environmental remediation.

机构信息

School of Life Science, Shaoxing University, Shaoxing 312000, PR China; MOE Key Laboratory of Resources and Environmental Systems Optimization, College of Environmental Science and Engineering, North China Electric Power University, Beijing 102206, PR China.

MOE Key Laboratory of Resources and Environmental Systems Optimization, College of Environmental Science and Engineering, North China Electric Power University, Beijing 102206, PR China.

出版信息

Sci Total Environ. 2022 Mar 10;811:152280. doi: 10.1016/j.scitotenv.2021.152280. Epub 2021 Dec 10.

Abstract

Environmental pollution has accelerated and intensified because of the acceleration of industrialization, therefore fabricating excellent materials to remove hazardous pollutants has become inevitable. MXenes as emerging transition metal nitrides, carbides or carbonitrides with high conductivity, hydrophilicity, excellent structural stability, and versatile surface chemistry, become ideal candidates for water purification and environmental remediation. Particularly, MXenes reveal excellent sorption capability and efficient reduction performance for various contaminants of wastewater. In this regard, a comprehensive understanding of the removal behaviors of MXene-based nanomaterials is necessary to explain how they remove various pollutants in water. The eliminate process of MXene-based nanomaterials is collectively influenced by the physicochemical properties of the materials themselves and the chemical properties of different contaminants. Therefore, in this review paper, the synthesis strategies and properties of MXene-based nanomaterials are briefly introduced. Then, the chemical properties, removal behaviors and interaction mechanisms of heavy metal ions, radionuclides, and organic pollutants by MXene-based nanomaterials are highlighted. The overview also emphasizes associated toxicity, secondary contamination, the challenges, and prospects of the MXene-based nanomaterials in the applications of water treatment. This review can supply valuable ideas for fabricating versatile MXene nanomaterials in eliminating water pollution.

摘要

由于工业化的加速,环境污染加速和加剧,因此制造出色的材料来去除危险污染物已成为必然。MXenes 作为新兴的过渡金属氮化物、碳化物或碳氮化物,具有高导电性、亲水性、优异的结构稳定性和多样的表面化学性质,成为水净化和环境修复的理想候选材料。特别是,MXenes 对各种废水污染物表现出优异的吸附能力和高效的还原性能。在这方面,全面了解基于 MXene 的纳米材料的去除行为对于解释它们如何去除水中的各种污染物是必要的。基于 MXene 的纳米材料的去除过程受到材料本身的物理化学性质和不同污染物的化学性质的共同影响。因此,在这篇综述论文中,简要介绍了基于 MXene 的纳米材料的合成策略和性质。然后,重点介绍了基于 MXene 的纳米材料对重金属离子、放射性核素和有机污染物的化学性质、去除行为和相互作用机制。综述还强调了与水疗应用相关的毒性、二次污染、挑战和 MXene 基纳米材料的前景。这篇综述可以为制造多功能 MXene 纳米材料以消除水污染提供有价值的思路。

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