Kusch Gunnar, Comish Ella J, Loeto Kagiso, Hammersley Simon, Kappers Menno J, Dawson Phil, Oliver Rachel A, Massabuau Fabien C-P
Department of Materials Science and Metallurgy, University of Cambridge, Cambridge CB3 0FS, UK.
Photon Science Institute, Department of Electrical and Electronic Engineering, School of Engineering, The University of Manchester, Manchester, M13 9PL, UK.
Nanoscale. 2022 Jan 6;14(2):402-409. doi: 10.1039/d1nr06088k.
Time-resolved cathodoluminescence offers new possibilities for the study of semiconductor nanostructures - including defects. The versatile combination of time, spatial, and spectral resolution of the technique can provide new insights into the physics of carrier recombination at the nanoscale. Here, we used power-dependent cathodoluminescence and temperature-dependent time-resolved cathodoluminescence to study the carrier dynamics at trench defects in InGaN quantum wells - a defect commonly found in III-nitride structures. The measurements show that the emission properties of trench defects closely relate to the depth of the related basal plane stacking fault within the quantum well stack. The study of the variation of carrier decay time with detection energy across the emission spectrum provides strong evidence supporting the hypothesis that strain relaxation of the quantum wells enclosed within the trench promotes efficient radiative recombination even in the presence of an increased indium content. This result shines light on previously reported peculiar emission properties of the defect, and illustrates the use of cathodoluminescence as a powerful adaptable tool for the study of defects in semiconductors.
时间分辨阴极发光为研究半导体纳米结构(包括缺陷)提供了新的可能性。该技术在时间、空间和光谱分辨率方面的多功能组合能够为纳米尺度下载流子复合的物理过程提供新的见解。在此,我们利用功率相关的阴极发光和温度相关的时间分辨阴极发光来研究InGaN量子阱中沟槽缺陷处的载流子动力学——这种缺陷在III族氮化物结构中很常见。测量结果表明,沟槽缺陷的发光特性与量子阱堆叠中相关基面堆垛层错的深度密切相关。对发射光谱上载流子衰减时间随探测能量变化的研究提供了有力证据,支持了这样的假设:即使在铟含量增加的情况下,沟槽内量子阱的应变弛豫仍能促进高效的辐射复合。这一结果揭示了此前报道的该缺陷独特的发光特性,并说明了阴极发光作为一种强大的适应性工具在研究半导体缺陷方面的应用。