Gu Xiao-Hua, Meng Yu-Quan, Chang Hui, Bai Tian-Xiang, Ma Sheng-Guo, Zhang Yong-Qiang, Song Wei-Dong, Li Zhi-Qiang
Center of Manufacture and Testing, AECC Commercial Aircraft Engine Co., Ltd., Shanghai 200241, China.
Institute of Applied Mechanics, College of Mechanical and Vehicle Engineering, Taiyuan University of Technology, Taiyuan 030024, China.
Materials (Basel). 2021 Dec 9;14(24):7574. doi: 10.3390/ma14247574.
The synthesis of lightweight yet strong-ductile materials has been an imperative challenge in alloy design. In this study, the CoCrNi-based medium-entropy alloys (MEAs) with added Al and Si were manufactured by vacuum arc melting furnace subsequently followed by cool rolling and anneal process. The mechanical responses of CoCrNiAlSi MEAs under quasi-static (1 × 10 s) tensile strength showed that MEAs had an outstanding balance of yield strength, ultimate tensile strength, and elongation. The yield strength, ultimate tensile strength, and elongation were increased from 480 MPa, 900 MPa, and 58% at 298 K to 700 MPa, 1250 MPa, and 72% at 77 K, respectively. Temperature dependencies of the yield strength and strain hardening were investigated to understand the excellent mechanical performance, considering the contribution of lattice distortions, deformation twins, and microbands. Severe lattice distortions were determined to play a predominant role in the temperature-dependent yield stress. The Peierls barrier height increased with decreasing temperature, owing to thermal vibrations causing the effective width of a dislocation core to decrease. Through the thermodynamic formula, the stacking fault energies were calculated to be 14.12 mJ/m and 8.32 mJ/m at 298 K and 77 K, respectively. In conclusion, the enhanced strength and ductility at cryogenic temperature can be attributed to multiple deformation mechanisms including dislocations, extensive deformation twins, and microbands. The synergistic effect of multiple deformation mechanisms lead to the outstanding mechanical properties of the alloy at room and cryogenic temperature.
合成轻质且兼具高强度和良好延展性的材料一直是合金设计中一项紧迫的挑战。在本研究中,添加了铝和硅的钴铬镍基中熵合金(MEA)通过真空电弧熔炼炉制造,随后进行冷轧和退火处理。钴铬镍铝硅中熵合金在准静态(1×10⁻³s)拉伸强度下的力学响应表明,该中熵合金在屈服强度、极限抗拉强度和伸长率方面具有出色的平衡。屈服强度、极限抗拉强度和伸长率分别从298K时的480MPa、900MPa和58%提高到77K时的700MPa、1250MPa和72%。考虑到晶格畸变、变形孪晶和微带的贡献,研究了屈服强度和应变硬化的温度依赖性,以了解其优异的力学性能。确定严重的晶格畸变在与温度相关的屈服应力中起主要作用。由于热振动导致位错核心的有效宽度减小,派尔斯势垒高度随温度降低而增加。通过热力学公式计算得出,在298K和77K时堆垛层错能分别为14.12mJ/m²和8.32mJ/m²。总之,低温下强度和延展性的增强可归因于包括位错、大量变形孪晶和微带在内的多种变形机制。多种变形机制的协同作用导致该合金在室温和低温下具有出色的力学性能。