Fu Jia, Chen Su
School of Material of Science and Engineering, Xi'an Shiyou University, Xi'an 710065, China.
School of Material of Science and Engineering, Taiyuan University of Science and Technology, Taiyuan 030024, China.
Materials (Basel). 2021 Dec 15;14(24):7760. doi: 10.3390/ma14247760.
In the present study, different solid solution and aging processes of as-cast and as-compressed ZM6 (MgNdZnZr) alloy were designed, and the microstructure and precipitation strengthening mechanisms were discussed. After the pre-aging treatment, a large amount of G.P. zones formed in the α-Mg matrix over the course of the subsequent secondary G.P. prescription, where the fine and dispersed Mg(Nd,Zn) phases were precipitated at the grain boundaries. The pre-aging and secondary aging processes resulted in the Mg(Nd,Zn) phase becoming globular, preventing grain boundary sliding and decreasing grain boundary diffusion. Meanwhile, precipitation phase â″(MgNd) demonstrated a coherent relationship with the α-Mg matrix after the pre-aging process, and after the secondary aging phase, MgNd increases and became semi-coherent in the matrix. Compared to an as-cast ZM6 alloy, the yield strength of the as-compressed ZM6 alloy increased sharply due to an increase in the yield strength that was proportional to the particle spacing, where the dislocation bypassed the second phase particle. Compared to the single-stage aging process, the two-stage aging process greatly improved the mechanical properties of both the as-cast and as-compressed ZM6 alloys. The difference between the as-cast and as-compressed states is that an as-compressed ZM6 alloy with more dislocations and twins has more dispersed precipitates in the G.P. zones after secondary aging, meaning that it is greatly strengthened after the two-stage aging treatment process.
在本研究中,设计了铸态和压缩态ZM6(MgNdZnZr)合金的不同固溶和时效工艺,并讨论了其微观结构和析出强化机制。预时效处理后,在随后的二次时效过程中,α-Mg基体中形成了大量G.P.区,细小且弥散的Mg(Nd,Zn)相在晶界析出。预时效和二次时效过程使Mg(Nd,Zn)相变为球状,抑制了晶界滑动并降低了晶界扩散。同时,析出相β″(MgNd)在预时效后与α-Mg基体呈现共格关系,二次时效后,MgNd增多并在基体中变为半共格。与铸态ZM6合金相比,压缩态ZM6合金的屈服强度急剧增加,这是由于屈服强度的增加与粒子间距成正比,位错绕过第二相粒子。与单级时效工艺相比,两级时效工艺极大地改善了铸态和压缩态ZM6合金的力学性能。铸态和压缩态之间的差异在于,具有更多位错和孪晶的压缩态ZM6合金在二次时效后的G.P.区中有更多弥散析出物,这意味着在两级时效处理后其得到了极大强化。