Dipartimento di Scienze Fisiche e Chimiche, Università degli Studi dell'Aquila, 67100 L'Aquila, Italy.
Dipartimento di Ingegneria Industriale e dell'Informazione e di Economia, Università degli Studi dell'Aquila, 67100 L'Aquila, Italy.
Int J Environ Res Public Health. 2021 Dec 10;18(24):13041. doi: 10.3390/ijerph182413041.
Non-renewable fossil fuels and the air pollution associated with their combustion have made it necessary to develop fuels that are environmentally friendly and produced from renewable sources. In addition, global warming and climate change have brought to the attention of many countries the need to develop programs and reforms, such as the 2030 Agenda of the United Nations and the European Green Deal, that finance and promote the conversion of all socio-economic activities in favor of sustainable and environmentally friendly development. These major projects include the development of non-polluting biofuels derived from renewable sources. Vegetable oils are a renewable source widely used to produce biofuels due to their high energy density and similar chemical composition to petroleum derivatives, making them the perfect feedstock for biofuel production. Green diesel and other hydrocarbon biofuels, obtained by the catalytic deoxygenation of vegetable oils, represent a sustainable alternative to mineral diesel, as they have physico-chemical properties similar to derived oil fuels. The catalyst, temperature, hydrogen pressure, and the type of vegetable oil can influence the type of biofuel obtained and its properties. The main aspects discussed in this review include the influence of the catalyst and reaction conditions on the catalytic deoxygenation reaction.
不可再生的化石燃料以及与它们燃烧相关的空气污染,使得开发环境友好且可再生资源燃料变得非常必要。此外,全球变暖和气候变化引起了许多国家的关注,需要制定计划和改革,例如联合国 2030 议程和欧洲绿色协议,为所有社会经济活动的转型提供资金并促进其向可持续和环境友好型发展转变。这些重大项目包括开发无污染的生物燃料,这些生物燃料来自可再生资源。植物油是一种可再生资源,由于其高能量密度和与石油衍生物相似的化学组成,被广泛用于生产生物燃料,是生物燃料生产的理想原料。通过植物油的催化脱氧作用得到的绿色柴油和其他碳氢化合物生物燃料是矿物柴油的可持续替代品,因为它们具有与衍生油燃料相似的物理化学性质。在本综述中讨论的主要方面包括催化剂和反应条件对催化脱氧反应的影响。