Białek Marzena, Fryga Julia
Institute of Chemistry, University of Opole, Oleska 48, 45-052 Opole, Poland.
Polymers (Basel). 2021 Dec 19;13(24):4456. doi: 10.3390/polym13244456.
This paper gives a short overview of homogeneous post-metallocene catalysts based on group 4 metal and vanadium complexes bearing multidentate ligands. It summarizes the catalytic behavior of those catalysts in copolymerization of ethylene with 1-olefins, with styrenic monomers and with α,ω-alkenols. The review is focused on finding correlations between the structure of a complex, its catalyst activity and comonomer incorporation ability, as well as the microstructure of the copolymer chains.
本文简要概述了基于第4族金属和带有多齿配体的钒配合物的均相后过渡金属催化剂。总结了这些催化剂在乙烯与1-烯烃、苯乙烯类单体以及α,ω-烯醇共聚反应中的催化行为。该综述着重于寻找配合物结构、其催化活性和共聚单体插入能力之间的相关性，以及共聚物链的微观结构。
