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烯烃-苯乙烯共聚物

Olefin⁻Styrene Copolymers.

作者信息

Galdi Nunzia, Buonerba Antonio, Oliva Leone

机构信息

Dipartimento di Chimica e Biologia "Adolfo Zambelli", Università degli Studi di Salerno, via Giovanni Paolo II, 84084 Fisciano, Italy.

出版信息

Polymers (Basel). 2016 Nov 19;8(11):405. doi: 10.3390/polym8110405.

DOI:10.3390/polym8110405
PMID:30974682
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC6432018/
Abstract

In this review are reported some of the most relevant achievements in the chemistry of the ethylene⁻styrene copolymerization and in the characterization of the copolymer materials. Focus is put on the relationship between the structure of the catalyst and that of the obtained copolymer. On the other hand, the wide variety of copolymer architecture is related to the properties of the material and to the potential utility.

摘要

本综述报道了乙烯-苯乙烯共聚化学及共聚物材料表征方面的一些最相关成果。重点关注催化剂结构与所得共聚物结构之间的关系。另一方面,共聚物结构的多样性与材料性能及潜在用途相关。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8b0d/6432018/950e2d5c5ec4/polymers-08-00405-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8b0d/6432018/8a671bd70ed2/polymers-08-00405-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8b0d/6432018/5ed404eb8bd0/polymers-08-00405-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8b0d/6432018/56d89c64dc93/polymers-08-00405-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8b0d/6432018/41cdee251779/polymers-08-00405-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8b0d/6432018/a24c5f6997f4/polymers-08-00405-sch001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8b0d/6432018/02dd5e784c0b/polymers-08-00405-sch002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8b0d/6432018/08245e12f097/polymers-08-00405-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8b0d/6432018/950e2d5c5ec4/polymers-08-00405-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8b0d/6432018/8a671bd70ed2/polymers-08-00405-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8b0d/6432018/5ed404eb8bd0/polymers-08-00405-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8b0d/6432018/56d89c64dc93/polymers-08-00405-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8b0d/6432018/41cdee251779/polymers-08-00405-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8b0d/6432018/a24c5f6997f4/polymers-08-00405-sch001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8b0d/6432018/02dd5e784c0b/polymers-08-00405-sch002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8b0d/6432018/08245e12f097/polymers-08-00405-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8b0d/6432018/950e2d5c5ec4/polymers-08-00405-g006.jpg

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本文引用的文献

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Awakening a dormant catalyst: salicylaldimine systems for ethene/tert-butylstyrene copolymerization.唤醒休眠催化剂:用于乙烯/叔丁基苯乙烯共聚的水杨醛亚胺体系
Dalton Trans. 2008 Dec 28(48):6883-5. doi: 10.1039/b818829g. Epub 2008 Nov 10.
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Penultimate effect in ethylene-styrene copolymerization and the discovery of highly active ethylene-styrene catalysts with increased styrene reactivity.乙烯-苯乙烯共聚中的倒数第二个效应以及具有增强苯乙烯反应活性的高活性乙烯-苯乙烯催化剂的发现。
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Living copolymerization of ethylene with styrene catalyzed by (cyclopentadienyl)(ketimide)titanium(IV) complex--MAO catalyst system.
间规聚苯乙烯-聚乙烯嵌段共聚物的合成与表征
Polymers (Basel). 2019 Apr 16;11(4):698. doi: 10.3390/polym11040698.
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High Conversion of Styrene, Ethylene, and Hydrogen to Linear Monoalkylbenzenes.高转化率的苯乙烯、乙烯和氢气生成直链单烷基苯。
Molecules. 2018 May 25;23(6):1260. doi: 10.3390/molecules23061260.
(环戊二烯基)(酮亚胺)钛(IV)配合物 - 甲基铝氧烷催化剂体系催化乙烯与苯乙烯的活性共聚反应
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