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VIZSLA——用于实验室天体化学的多功能冰之字形升华装置

VIZSLA-Versatile Ice Zigzag Sublimation Setup for Laboratory Astrochemistry.

作者信息

Bazsó Gábor, Csonka István Pál, Góbi Sándor, Tarczay György

机构信息

Wigner Research Centre for Physics, P.O. Box 49, H-1525 Budapest, Hungary.

MTA-ELTE Lendület Laboratory Astrochemistry Research Group, Institute of Chemistry, ELTE Eötvös Loránd University, H-1518 Budapest, Hungary.

出版信息

Rev Sci Instrum. 2021 Dec 1;92(12):124104. doi: 10.1063/5.0061762.

DOI:10.1063/5.0061762
PMID:34972403
Abstract

In this article, a new multi-functional high-vacuum astrophysical ice setup, VIZSLA (Versatile Ice Zigzag Sublimation Setup for Laboratory Astrochemistry), is introduced. The instrument allows for the investigation of astrophysical processes both in a low-temperature para-H matrix and in astrophysical analog ices. In the para-H matrix, the reaction of astrochemical molecules with H atoms and H ions can be studied effectively. For the investigation of astrophysical analog ices, the setup is equipped with various irradiation and particle sources: an electron gun for modeling cosmic rays, an H atom beam source, a microwave H atom lamp for generating H Lyman-α radiation, and a tunable (213-2800 nm) laser source. For analysis, an FT-IR (and a UV-visible) spectrometer and a quadrupole mass analyzer are available. The setup has two cryostats, offering novel features for analysis. Upon the so-called temperature-programmed desorption (TPD), the molecules, desorbing from the substrate of the first cryogenic head, can be mixed with Ar and can be deposited onto the substrate of the other cryogenic head. The efficiency of the redeposition was measured to be between 8% and 20% depending on the sample and the redeposition conditions. The well-resolved spectrum of the molecules isolated in an Ar matrix serves a unique opportunity to identify the desorbing products of a processed ice. Some examples are provided to show how the para-H matrix experiments and the TPD-matrix-isolation recondensation experiments can help understand astrophysically important chemical processes at low temperatures. It is also discussed how these experiments can complement the studies carried out by using similar astrophysical ice setups.

摘要

在本文中,介绍了一种新型多功能高真空天体物理冰装置VIZSLA(用于实验室天体化学的通用冰之字形升华装置)。该仪器能够在低温对氢基质和天体物理模拟冰中研究天体物理过程。在对氢基质中,可以有效地研究天体化学分子与氢原子和氢离子的反应。为了研究天体物理模拟冰,该装置配备了各种辐照和粒子源:用于模拟宇宙射线的电子枪、氢原子束源、用于产生氢莱曼-α辐射的微波氢原子灯以及可调谐(213 - 2800纳米)激光源。用于分析的有傅里叶变换红外(和紫外 - 可见)光谱仪以及四极质量分析仪。该装置有两个低温恒温器,具有新颖的分析功能。在所谓的程序升温脱附(TPD)过程中,从第一个低温探头的基底解吸出来的分子可以与氩气混合,并沉积到另一个低温探头的基底上。根据样品和再沉积条件,再沉积效率测量值在8%至20%之间。在氩基质中分离出的分子的高分辨率光谱为识别经过处理的冰的解吸产物提供了独特的机会。提供了一些例子来说明对氢基质实验和TPD - 基质隔离再冷凝实验如何有助于理解低温下天体物理学上重要的化学过程。还讨论了这些实验如何补充使用类似天体物理冰装置所进行的研究。

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