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微泡在不使用化学剂的情况下有效清洁金属表面。

Microbubbles for Effective Cleaning of Metal Surfaces Without Chemical Agents.

机构信息

School of Environmental Science and Engineering, Tongji University, 1239 Siping Road, Shanghai 200092, P. R. China.

School of Environmental Science and Engineering, State Key Laboratory of Control and Resource Reuse, Tongji University, 1239 Siping Road, Shanghai 200092, PR China.

出版信息

Langmuir. 2022 Jan 18;38(2):769-776. doi: 10.1021/acs.langmuir.1c02769. Epub 2022 Jan 5.

Abstract

Traditional cleaning methods involving surfactants and ultrasound generate large amounts of wastewater. Microbubbles offer a more eco-friendly technology for interface cleaning. Here, we explored the efficiency of microbubbles for cleaning oil from metal surfaces. Air microbubbles at concentrations as high as 10 particles/mL were generated by hydrodynamic cavitation. Under optimal conditions, cleaning efficiencies for the removal of oil from carbon-steel and stainless-steel surfaces were 78.5 and 49.8% after 15 min, respectively, compared to only 6.5 and 9.9% without microbubbles. Additionally, combining microbubble treatment with the ultrasonic method achieved a higher efficiency than ultrasonic cleaning alone, achieving an efficiency of 85.5% after 3 min compared to 69.0%. The mechanism of microbubble cleaning was determined using a fluorescence observation system, and a model was established to describe the cleaning process. The use of microbubbles produced less emulsified oil wastewater because the oil that attaches to the microbubble surface floats with the bubbles to the surface of the cleaning water, where it can be removed, allowing for water recycling. This novel microbubble cleaning technology, which both enhances cleaning efficiency and reduces wastewater production, represents a viable and eco-friendly option for degreasing processes.

摘要

传统的涉及表面活性剂和超声波的清洁方法会产生大量废水。微泡提供了一种更环保的界面清洁技术。在这里,我们探索了微泡用于清洁金属表面油污的效率。通过流体动力空化产生浓度高达 10 个/毫升的空气微泡。在最佳条件下,与没有微泡的情况相比,15 分钟后,碳钢和不锈钢表面的除油效率分别达到 78.5%和 49.8%,而分别只有 6.5%和 9.9%。此外,将微泡处理与超声方法结合使用,其效率比单独超声清洗更高,3 分钟后达到 85.5%,而 69.0%。使用荧光观察系统确定了微泡清洁的机制,并建立了一个模型来描述清洁过程。由于附着在微泡表面的油随气泡浮到清洁水的表面,因此可以将其去除,从而可以实现水循环,因此使用微泡产生的乳化含油废水较少。这种新颖的微泡清洁技术既能提高清洁效率,又能减少废水的产生,是一种可行且环保的除油工艺选择。

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