University of Montana, 32 Campus Drive, Missoula, MT, USA.
Chem Commun (Camb). 2022 Jan 27;58(9):1378-1381. doi: 10.1039/d1cc05475a.
Recent results indicate a halogen bond donor is strengthened through direct interaction with a hydrogen bond to the electron-rich belt of the halogen. Here, this Hydrogen Bond enhanced Halogen Bond (HBeXB) plays a clear role in a catalyst. Our HBeXB catalyst improves product conversion in a halide abstraction reaction over a traditional halogen bonding derivative.
最近的研究结果表明，卤素键供体通过与富电子的卤素带的氢键直接相互作用而增强。在这里，这种氢键增强的卤素键 (HBeXB) 在催化剂中起着明显的作用。我们的 HBeXB 催化剂提高了卤化物消除反应中产物的转化率，优于传统的卤素键衍生物。
