Hashem Md Abul, Hasan Md Anik, Momen Md Abdul, Payel Sofia, Hasan Mehedi, Shaikh Md Zillur Rahaman
Department of Leather Engineering, Khulna University of Engineering & Technology (KUET), Khulna, 9203, Bangladesh.
Department of Civil Engineering, Bangladesh University of Engineering and Technology (BUET), Dhaka, 1000, Bangladesh.
Environ Sci Pollut Res Int. 2022 May;29(21):31278-31292. doi: 10.1007/s11356-022-18544-0. Epub 2022 Jan 10.
The regular practice of using sodium chloride to preserve raw animal skin triggers increasing salinity and total dissolved solids (TDS) in the surface and groundwater during rehydration soaking operations. The process disrupts the lives of animals, plants, and human beings. This paper is focused on the phyto-based short-term preservation of goatskin to reduce salinity in tannery soaking operations. The indigenous Persicaria hydropiper leaf was investigated to assess the preservation of animal skin to diminish salinity and TDS of tannery soaking wastewater. Methanol-extracted leaf was characterized by GC-MS and FTIR for chemical composition analysis and affiliated functional groups. Fresh goatskins were preserved at the preliminary, laboratory, and pilot-scale scenarios to establish the best possible mixture and monitor the moisture and nitrogen content, shrinkage temperature, microorganism analysis, and pollution load at each level. The processed leathers derived from the preserved skins with an optimal mixture of 10% leaf paste with 8% salt and conventional 50% salt were tested for their physical strength. Finally, the modification in fiber structure due to the varieties of preserving chemicals was evaluated through a scanning electron microscope (SEM) and detected insignificant variation of leather fibers. The findings reported in this study can be applied to the industrial level and remove certain amounts of salinity and TDS from tannery soaking wastewater.
常规使用氯化钠保存生兽皮的做法,在复水浸泡操作过程中会导致地表水和地下水中的盐度及总溶解固体(TDS)不断增加。这一过程扰乱了动物、植物和人类的生活。本文聚焦于以植物为基础的山羊皮短期保存方法,以降低制革厂浸泡操作中的盐度。对本土的水蓼叶进行了研究,以评估其对兽皮的保存效果,从而减少制革厂浸泡废水的盐度和TDS。采用气相色谱-质谱联用仪(GC-MS)和傅里叶变换红外光谱仪(FTIR)对甲醇提取的叶片进行化学成分分析及相关官能团鉴定。在初步、实验室和中试规模场景下对新鲜山羊皮进行保存,以确定最佳混合比例,并监测每个阶段的水分和氮含量、收缩温度、微生物分析及污染负荷。对用10%叶糊与8%盐的最佳混合物以及传统50%盐保存的兽皮所制成的皮革进行物理强度测试。最后,通过扫描电子显微镜(SEM)评估因保存化学品种类不同而导致的纤维结构变化,结果发现皮革纤维的变化不显著。本研究报告的结果可应用于工业层面,从制革厂浸泡废水中去除一定量的盐度和TDS。