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关于低钠盐动物皮保存用聚丙烯酸钠(SPA)的研究。

Studies on the use of sodium polyacrylate (SPA) for low-salt animal skin preservation.

机构信息

Chemical Engineering Department, CSIR-Central Leather Research Institute, Adyar, Chennai, Tamil Nadu, 600020, India.

Leather Processing Division, CSIR-Central Leather Research Institute, Adyar, Chennai, 600020, India.

出版信息

Environ Sci Pollut Res Int. 2019 Sep;26(26):27100-27111. doi: 10.1007/s11356-019-05871-y. Epub 2019 Jul 17.

Abstract

Salt-based preservation is practiced for decades in the leather industry because of its versatility, cost-effectiveness, and availability. The salt removed from the soaking process causes significant pollution including organic and elevated total dissolved solids (TDS). Hence, a low-salt skin preservation method using commercial sodium polyacrylate with a reduced quantity of sodium chloride aiming to retain leather properties and pollution reduction was the principal focus of the study. Commercial sodium polyacrylate initially characterized for water absorption capacity along with structural and functional properties is confirmed by NMR and IR spectroscopic techniques. In preliminary experiments, the process parameters attained optimized conditions of sodium polyacrylate (SPA) quantity (5%), a minimal amount of salt (15%), and contact time (4 h) required for skin preservation. Besides, reusability studies after SPA recovery (95%) were applied to skins with an optimized quantity of SPA and salt subsequently stored for 15 days along with control (40% salt). The results revealed that SPA with low salt aided an adequate curing efficiency with a substantial reduction (> 65%) of TDS and comparable physical and organoleptic properties on par with the conventional method. Overall, SPA supported low-salt skin preservation reduces pollutant load (TDS) caused due to using of 40% sodium chloride in the conventional curing process.

摘要

盐基保存法在皮革行业已经应用了几十年,因为它具有多功能性、成本效益高和可用性强的特点。盐基从浸泡过程中去除,会导致严重的污染,包括有机物和高总溶解固体(TDS)。因此,本研究的主要重点是使用商业聚丙烯酸钠和减少氯化钠的用量,开发一种低盐保存皮革的方法,以保留皮革的特性和减少污染。商业聚丙烯酸钠最初具有吸水性以及结构和功能特性,这通过 NMR 和 IR 光谱技术得到了证实。在初步实验中,确定了达到优化条件的工艺参数,即聚丙烯酸钠(SPA)的用量(5%)、盐的最小用量(15%)和皮肤保存所需的接触时间(4 小时)。此外,还对 SPA 回收后的可重复使用性进行了研究(95%),并将 SPA 和盐的优化用量应用于随后储存 15 天的皮革,以及与对照(40%盐)进行比较。结果表明,低盐 SPA 有助于实现充分的固化效率,显著降低 TDS(>65%),并且物理和感官性能与传统方法相当。总体而言,使用 SPA 支持低盐保存可以减少传统固化过程中使用 40%氯化钠所带来的污染物负荷(TDS)。

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