Wang Xiaohui, Xu Li, Yang Rui, Huang Runzhou, Mao Haiyan
College of Materials Science and Engineering, Nanjing Forestry University, Nanjing 210037, China.
Department of Chemical and Biomolecular Engineering, University of California, Berkeley, CA 94720, USA.
Int J Mol Sci. 2021 Dec 22;23(1):60. doi: 10.3390/ijms23010060.
Styrene acrylic emulsions (SAEs) have emerged as a promising material for water-based coatings. However, they are still limited by their own defects in practical applications, poor weatherability, and degradation of performance at lower or higher temperatures. Here, we introduce a facile approach to producing fluorescent carbon quantum dots (CQDs) from wood processing residues and fabricating fluorescent CQD/SAE coating films via emulsion-casting. The addition of the fluorescent CQDs enhanced the optical performance of the CQD/SAE coating films. The fluorescent CQDs were prepared via a hydrothermal approach and were obtained after heating at 180 °C for 6 h at a reaction concentration of 50 mg/mL. The synthesized CQDs resulted in a high fluorescence, and the CQDs had an average size of 1.63 nm. Various concentrations of the fluorescent CQDs were doped into the SAE coating film, which improved its optical properties. We also characterized and discussed the products and then explored their optical properties. This study presents the potential of fluorescent CQD/SAE coating films for applications in anti-counterfeiting coatings, fluorescent adhesives, and papermaking.
苯乙烯丙烯酸乳液(SAEs)已成为水性涂料中一种很有前景的材料。然而,在实际应用中,它们仍然受到自身缺陷的限制,如耐候性差,以及在较低或较高温度下性能下降。在此,我们介绍一种从木材加工残渣制备荧光碳量子点(CQDs)的简便方法,并通过乳液流延法制备荧光CQD/SAE涂膜。荧光CQDs的添加增强了CQD/SAE涂膜的光学性能。荧光CQDs通过水热法制备,在反应浓度为50 mg/mL的条件下,于180℃加热6小时后得到。合成的CQDs具有高荧光性,其平均尺寸为1.63 nm。将不同浓度的荧光CQDs掺杂到SAE涂膜中,改善了其光学性能。我们还对产物进行了表征和讨论,然后探究了它们的光学性质。本研究展示了荧光CQD/SAE涂膜在防伪涂料、荧光胶粘剂和造纸领域的应用潜力。