A Review on Recent Advances in the Applications of Boron-Doped Diamond Electrochemical Sensors in Food Analysis.

The usage of boron-doped diamond (BDD) material has found to be very attractive in modern electroanalytical methods and received massive consideration as perspective electrochemical sensor due to its outstanding (electro)chemical properties. These generally known facilities include large potential window, low background currents, ability to withstand extreme potentials and strong tendency to resist fouling compared to conventional carbon-based electrodes. As evidence of superiority of this material, couple of reviews describing the overview of various applications of BDD electrodes in the field of analytical and material chemistry has been reported in scientific literature during last decade. However, herein proposed review predominantly focuses on the most recent developments (from 2009 to 2020) dealing with the application of BDD as an advanced and environmental-friendly sensor platform in food analysis. The main method characteristics of analysis of various organic food components with different chemical properties, including additives, flavor and aroma components, phenolic compounds, flavonoids and pesticides in food matrices are described in more details. The importance of BDD surface termination, presence of sp content and boron doping level on electrochemical sensing is discussed. Apart from this, a special attention is paid to the evaluation of main analytical characteristics of the BDD electrochemical sensor in single- and multi-analyte detection mode in food analysis. The recent achievements in the utilizing of BDD electrodes in amperometric detection coupled to flow injection analysis, batch injection analysis, and high-performance liquid chromatography are also commented. Moreover, actual trends in sample preparation techniques prior to electrochemical sensing in food analysis are referred.