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通过丝网印刷银浆缓冲层制备的单壁碳纳米管阴极的增强场发射

Enhanced Field Emission of Single-Wall Carbon Nanotube Cathode Prepared by Screen Printing with a Silver Paste Buffer Layer.

作者信息

Jiang Ruirui, Liu Jianlong, Yang Kaiqiang, Zhao Jing, Zeng Baoqing

机构信息

National Key Laboratory of Science and Technology on Vacuum Electronics, School of Electronic Science and Engineering, University of Electronic Science and Technology of China, Chengdu 610051, China.

出版信息

Nanomaterials (Basel). 2022 Jan 4;12(1):165. doi: 10.3390/nano12010165.

Abstract

A high emission current with relatively low operating voltage is critical for field emission cathodes in vacuum electronic devices (VEDs). This paper studied the field emission performance of single-wall carbon nanotube (SWCNT) cold cathodes prepared by screen printing with a silver paste buffer layer. The buffer layer can both enforce the adhesion between the SWCNTs and substrate, and decrease their contact resistance, so as to increase emission current. Compared with paste mixing CNTs and screen printed cathodes, the buffer layer can avoid excessive wrapping of CNTs in the silver slurry and increase effective emission area to reduce the operating voltage. The experimental results show that the turn-on field of the screen-printed SWCNT cathodes is 0.9 V/μm, which is lower than that of electrophoretic SWCNT cathodes at 2.0 V/μm. Meanwhile, the maximum emission current of the screen-printed SWCNT cathodes reaches 5.55 mA at DC mode and reaches 10.4 mA at pulse mode, which is an order magnitude higher than that of electrophoretic SWCNTs emitters. This study also shows the application insight of small or medium-power VEDs.

摘要

对于真空电子器件(VED)中的场发射阴极而言,具有相对较低工作电压的高发射电流至关重要。本文研究了通过丝网印刷制备的带有银浆缓冲层的单壁碳纳米管(SWCNT)冷阴极的场发射性能。该缓冲层既能增强SWCNT与基底之间的附着力,又能降低它们的接触电阻,从而增加发射电流。与将碳纳米管与银浆混合后丝网印刷的阴极相比,缓冲层可以避免碳纳米管在银浆中过度缠绕,并增加有效发射面积以降低工作电压。实验结果表明,丝网印刷的SWCNT阴极的开启电场为0.9 V/μm,低于电泳法制备的SWCNT阴极的2.0 V/μm。同时,丝网印刷的SWCNT阴极在直流模式下的最大发射电流达到5.55 mA,在脉冲模式下达到10.4 mA,比电泳法制备的SWCNT发射极高出一个数量级。该研究还展示了中小功率VED的应用前景。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d81a/8746308/ef3defd360ef/nanomaterials-12-00165-g001.jpg

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