Chatzichristos Aris, Hassan Jamal
Department of Physics, Khalifa University, Abu Dhabi 127788, United Arab Emirates.
Nanomaterials (Basel). 2022 Jan 5;12(1):174. doi: 10.3390/nano12010174.
Confined water inside carbon nanotubes (CNTs) has attracted a lot of attention in recent years, amassing as a result a very large number of dedicated studies, both theoretical and experimental. This exceptional scientific interest can be understood in terms of the exotic properties of nanoconfined water, as well as the vast array of possible applications of CNTs in a wide range of fields stretching from geology to medicine and biology. This review presents an overreaching narrative of the properties of water in CNTs, based mostly on results from systematic nuclear magnetic resonance (NMR) and molecular dynamics (MD) studies, which together allow the untangling and explanation of many seemingly contradictory results present in the literature. Further, we identify still-debatable issues and open problems, as well as avenues for future studies, both theoretical and experimental.
近年来,碳纳米管(CNTs)内的受限水引起了广泛关注,因此积累了大量专门的理论和实验研究。这种特殊的科学兴趣可以从纳米受限水的奇异特性以及碳纳米管在从地质到医学和生物学等广泛领域的大量可能应用方面来理解。本综述主要基于系统的核磁共振(NMR)和分子动力学(MD)研究结果,对碳纳米管中水的性质进行了全面的阐述,这些研究共同使得能够梳理和解释文献中许多看似矛盾的结果。此外,我们还确定了仍有争议的问题和未解决的问题,以及未来理论和实验研究的途径。