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在带电水/有机界面上,细胞色素的混沌调制电化学催化活性的起源。

On the origin of chaotrope-modulated electrocatalytic activity of cytochrome at electrified aqueous|organic interfaces.

机构信息

The Bernal Institute, University of Limerick (UL), Limerick V94 T9PX, Ireland.

Department of Chemical Sciences, School of Natural Sciences, University of Limerick (UL), Limerick V94 T9PX, Ireland.

出版信息

Chem Commun (Camb). 2022 Mar 8;58(20):3270-3273. doi: 10.1039/d1cc05293d.

Abstract

Electrochemical, spectroscopic and computational methods are used to demonstrate that electrified aqueous|organic interfaces are a suitable bio-mimetic platform to study and contrast the accelerated electrocatalytic activity of cytochrome towards the production of reactive oxygen species (ROS) in the presence of denaturing agents such as guanidinium chloride and urea.

摘要

电化学、光谱学和计算方法被用来证明,带电的水/有机界面是一个合适的仿生平台,可以用来研究和对比细胞色素 c 在存在变性剂(如盐酸胍和尿素)的情况下,对活性氧物质 (ROS) 的加速电催化活性。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cb66/8902681/74d30adaf741/d1cc05293d-s1.jpg

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