Cai Yanping, Jiang Shengjie, Dong Liqiu, Xu Xin
Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, P. R. China.
Department of Chemical Engineering, University College London, Torrington Place, London WC1E 7JE, UK.
Dalton Trans. 2022 Mar 8;51(10):3817-3827. doi: 10.1039/d1dt04117g.
Heteronuclear metal complexes comprising main group metals and transition metals have attracted widespread attention from researchers due to their applications in stoichiometric and catalytic activation of small molecules with possible cooperative effects. Herein, the advances of heterometallic complexes containing Mg- or Zn-metalloligands over the past ten years are reviewed. They consist of two parts: (i) synthetic approaches to heterometallic complexes. Only a brief discussion is made on the different Mg/Zn precursors since they have been summarized before. (ii) Stoichiometric and catalytic reactivities of heterometallic complexes containing Mg/Zn metalloligands. The exploration of the cooperative catalytic reaction of heterometallic complexes is still in its infancy, promising but challenging; thus, further investigations are required in the future.
由主族金属和过渡金属组成的异核金属配合物因其在小分子的化学计量和催化活化中可能存在的协同效应而受到研究人员的广泛关注。在此，综述了过去十年中含镁或锌金属配体的异金属配合物的研究进展。它们包括两个部分：（i）异金属配合物的合成方法。由于之前已经进行了总结，因此仅对不同的镁/锌前体进行简要讨论。（ii）含镁/锌金属配体的异金属配合物的化学计量和催化反应活性。异金属配合物的协同催化反应探索仍处于起步阶段，前景广阔但具有挑战性；因此，未来需要进一步研究。
