College of Chemistry and Materials Science, Hunan Agricultural University, Changsha 410128, China.
State Key Laboratory of Chemo/Biosensing and Chemometrics, and College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, China.
J Colloid Interface Sci. 2022 Jun;615:69-78. doi: 10.1016/j.jcis.2022.01.169. Epub 2022 Jan 29.
Engineering of electromagnetic wave absorbing materials featuring long-term durability in harsh outdoor environments (e.g., humidity, acid, and alkali conditions) is meaningful for their effective and sustainable implementation. Herein, morphology-controlled erbium oxide-reduced graphene oxide composites are designed for effective absorption of electromagnetic microwaves either in an acidic or alkaline environment. The engineered nanocomposites with chrysanthemum-like structures display good impedance matching, moderate attenuation constant, exchange resonance, natural resonance, multiple reflections, and polarization relaxations, therefore exhibiting excellent microwave absorption capacity with a minimum reflection loss of -37.18 dB and an effective absorption bandwidth of 5.1 GHz. In addition, the chrysanthemum-like composite also displays self-cleaning property, strong weatherability, and acid- and alkali-resistance, enabling sustained electromagnetic wave absorbing performance even in corrosive conditions (1 M HCl, 1 M NaOH). The findings indicate that, through structural engineering, erbium oxide-reduced graphene oxide composites can serve as a promising microwave absorber in harsh outdoor environments.
在恶劣的户外环境(如湿度、酸、碱条件)下,具有长期耐用性的电磁波吸收材料的工程设计对于其有效和可持续的实施具有重要意义。本文设计了形态可控的氧化铒还原氧化石墨烯复合材料,用于在酸性或碱性环境中有效吸收电磁波。具有菊花状结构的工程化纳米复合材料具有良好的阻抗匹配、适中的衰减常数、交换共振、自然共振、多次反射和极化松弛,因此表现出优异的微波吸收能力,最小反射损耗为-37.18dB,有效吸收带宽为 5.1GHz。此外,菊花状复合材料还具有自清洁性能、强耐候性和耐酸碱性能,即使在腐蚀性条件下(1M HCl、1M NaOH)也能保持持续的电磁波吸收性能。研究结果表明,通过结构工程,氧化铒还原氧化石墨烯复合材料可用作恶劣户外环境下有前途的微波吸收剂。