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磷酸钽催化剂上丙酮选择性转化为均三甲苯

Selective conversion of acetone to mesitylene over tantalum phosphate catalysts.

作者信息

Wu Zhiyi, Zhang Jian, Su Zerui, Lu Shiyao, Huang Jianbin, Liang Yehao, Tan Tianwei, Xiao Feng-Shou

机构信息

Beijing Advanced Innovation Center for Soft Matter, Science and Engineering, Beijing Key Laboratory of Bioprocess, National Energy R&D Center for Biorefinery, College of Life Science and Technology, Beijing University of Chemical Technology, 15 BeiSanhuan East Road, ChaoYang District, Beijing, China.

出版信息

Chem Commun (Camb). 2022 Feb 24;58(17):2862-2865. doi: 10.1039/d2cc00016d.

Abstract

We report the synthesis of a tantalum phosphate catalyst with abundant strong acid sites, which is very active for the catalytic conversion of acetone into mesitylene. Characterizations, kinetic studies, and theoretical results show a relationship between the acidic sites and catalytic performance in this reaction.

摘要

我们报道了一种具有大量强酸位点的磷酸钽催化剂的合成,该催化剂对丙酮催化转化为均三甲苯具有很高的活性。表征、动力学研究和理论结果表明了该反应中酸性位点与催化性能之间的关系。

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