Bahadoran Ashkan, Baghbadorani Nooshin Bahadoran, De Lile Jeffrey Roshan, Masudy-Panah Saeid, Sadeghi Behzad, Li Jinghan, Ramakrishna Seeram, Liu Qinglei, Janani Baadal Jushi, Fakhri Ali
State Key Laboratory of Metal Matrix Composite, Shanghai Jiao Tong University, Shanghai 200240, China.
Department of Chemical Engineering, Isfahan University of Technology, Isfahan 84156-83111, Iran.
J Photochem Photobiol B. 2022 Mar;228:112393. doi: 10.1016/j.jphotobiol.2022.112393. Epub 2022 Jan 20.
Ag doped SnO Nanostructure and immobilized on hyperbranched polypyrrole is investigated in this project. The product was synthesized by the hydrothermal synthesis method. The surface and structural characteristics of the product was studied by different instrumental analysis. The fabricated nanocomposites was utilized as a nano photocatalyst in the removal of methylene blue dye. The crystallography results depicts the triclinic phase of SnO with the crystallite size 36.3 nm. The band gap of the Ag-SnO/hyperbranched polypyrrole was found 1.50 eV from kubelka-munk measurements. The specific surface area was increased in the presence of the hyperbranched polypyrrole as compared to Ag-SnO samples. The photo-catalytic activity of composites was found 100.0% degradation of CR in 30 min under visible light irradiation. The catalytic kinetic was followed from the first kinetic model. Moreover, the Ag/SnO/hyperbranched polypyrrole was applied as a bactericidal agent against Streptococcus pneumoniae, and Pseudomonas aeruginosa bacteria. Determination of Streptococcus pyogenes as a pathogenic bacteria was investigated by using aptamer/Ag/SnO/hyperbranched polypyrrole in peroxidase activity. The detection limit of S. pyogenes was 71.0 CFU/mL by using the nano-aptamer.
本项目研究了Ag掺杂的SnO纳米结构及其固定在超支化聚吡咯上的情况。该产物通过水热合成法合成。通过不同的仪器分析研究了产物的表面和结构特征。制备的纳米复合材料被用作纳米光催化剂用于去除亚甲基蓝染料。晶体学结果表明SnO为三斜相,晶粒尺寸为36.3 nm。通过库贝尔卡-蒙克测量发现Ag-SnO/超支化聚吡咯的带隙为1.50 eV。与Ag-SnO样品相比,在超支化聚吡咯存在下比表面积增加。发现复合材料的光催化活性在可见光照射下30分钟内对CR的降解率为100.0%。催化动力学遵循一级动力学模型。此外,Ag/SnO/超支化聚吡咯被用作针对肺炎链球菌和铜绿假单胞菌的杀菌剂。通过使用适体/Ag/SnO/超支化聚吡咯的过氧化物酶活性研究了化脓性链球菌作为病原菌的测定。使用纳米适体时,化脓性链球菌的检测限为71.0 CFU/mL。