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无机卤化铅钙钛矿中的斯托克斯位移:现状与展望。

Stokes Shift in Inorganic Lead Halide Perovskites: Current Status and Perspective.

机构信息

Key Laboratory of Optoelectronic Devices and Systems of Ministry of Education and Guangdong Province, College of Physics and Optoelectronic Engineering, Shenzhen University, Shenzhen, China.

College of Electronics and Electrical Engineering, Shenzhen University, Shenzhen, China.

出版信息

ChemistryOpen. 2022 Mar;11(3):e202100285. doi: 10.1002/open.202100285. Epub 2022 Feb 11.

Abstract

Inorganic metal halide perovskite system is considered as a promising candidate for applications from display to biomedical industry. Intrinsic inorganic lead halides possess small Stokes shift or self-absorption, providing negative impact for both photo voltaic and biomedical applications. Therefore, the development of an inorganic halide perovskite system with large Stokes shift is a significant venture. This review aims to provide an updated survey of the Stokes shift phenomena in the inorganic lead halide perovskites. The first section focuses about the mechanism, the second section gives different approaches in preparing inorganic perovskites with distinct Stokes shift, while the third section highlights the potential applications in both photovoltaic and biomedical areas. This review provides deep insight about the importance and usefulness of such phenomena in inorganic lead halides, essential for various applications.

摘要

无机金属卤化物钙钛矿体系被认为是从显示到生物医学工业应用的有前途的候选者。本征无机铅卤化物具有小的斯托克斯位移或自吸收,这对光电和生物医学应用都有负面影响。因此,开发具有大斯托克斯位移的无机卤化物钙钛矿体系是一项重要的冒险。本综述旨在提供关于无机铅卤化物钙钛矿中斯托克斯位移现象的最新调查。第一节重点介绍了机制,第二节给出了用不同方法制备具有不同斯托克斯位移的无机钙钛矿的方法,而第三节则强调了在光电和生物医学领域的潜在应用。本综述深入了解了这种现象在无机铅卤化物中的重要性和有用性,这对各种应用是必不可少的。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3074/8889505/d3f282081b6e/OPEN-11-e202100285-g003.jpg

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