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基于石墨烯的纳米流体:生产参数对热物理性质和分散稳定性的影响

Graphene-Based Nanofluids: Production Parameter Effects on Thermophysical Properties and Dispersion Stability.

作者信息

Ali Naser

机构信息

Nanotechnology and Advanced Materials Program, Energy and Building Research Center, Kuwait Institute for Scientific Research, Safat 13109, Kuwait.

出版信息

Nanomaterials (Basel). 2022 Jan 22;12(3):357. doi: 10.3390/nano12030357.

DOI:10.3390/nano12030357
PMID:35159702
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC8838429/
Abstract

In this study, the thermophysical properties and dispersion stability of graphene-based nanofluids were investigated. This was conducted to determine the influence of fabrication temperature, nanomaterial concentration, and surfactant ratio on the suspension effective properties and stability condition. First, the nanopowder was characterized in terms of crystalline structure and size, morphology, and elemental content. Next, the suspensions were produced at 10 °C to 70 °C using different concentrations of surfactants and nanomaterials. Then, the thermophysical properties and physical stability of the nanofluids were determined. The density of the prepared nanofluids was found to be higher than their base fluid, but this property showed a decrease with the increase in fabrication temperature. Moreover, the specific heat capacity showed very high sensitivity toward the graphene and surfactant concentrations, where 28.12% reduction in the property was achieved. Furthermore, the preparation temperature was shown to be the primary parameter that effects the nanofluid viscosity and thermal conductivity, causing a maximum reduction of ~4.9% in viscosity and ~125.72% increase in thermal conductivity. As for the surfactant, using low concentration demonstrated a short-term stabilization capability, whereas a 1:1 weight ratio of graphene to surfactant and higher caused the dispersion to be physically stable for 45 consecutive days. The findings of this work are believed to be beneficial for further research investigations on thermal applications of moderate temperatures.

摘要

在本研究中,对石墨烯基纳米流体的热物理性质和分散稳定性进行了研究。开展此项研究是为了确定制备温度、纳米材料浓度和表面活性剂比例对悬浮液有效性质和稳定性条件的影响。首先,对纳米粉末的晶体结构、尺寸、形态和元素含量进行了表征。接下来,使用不同浓度的表面活性剂和纳米材料在10℃至70℃的温度下制备悬浮液。然后,测定了纳米流体的热物理性质和物理稳定性。发现所制备的纳米流体的密度高于其基础流体,但该性质随制备温度的升高而降低。此外,比热容对石墨烯和表面活性剂的浓度表现出非常高的敏感性,该性质降低了28.12%。此外,制备温度被证明是影响纳米流体粘度和热导率的主要参数,导致粘度最大降低约4.9%,热导率最大增加约125.72%。至于表面活性剂,使用低浓度表现出短期稳定能力,而石墨烯与表面活性剂的重量比为1:1及更高时,分散体在45天内保持物理稳定。相信这项工作的结果将有利于对中温热应用的进一步研究。

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