Kaban Burhan, Bagatur Sekvan, Soter Marcus, Hillmer Hartmut, Fuhrmann-Lieker Thomas
Institute of Nanostructure Technologies and Analytics (INA) and Center for Interdisciplinary Nanostructure Science and Technology (CINSaT), University of Kassel, Heinrich-Plett-Straße 40, 34132 Kassel, Germany.
Physical Chemistry of Nanomaterials, Institute of Chemistry and Center for Interdisciplinary Nanostructure Science and Technology (CINSaT), University of Kassel, Heinrich-Plett-Straße 40, 34132 Kassel, Germany.
Polymers (Basel). 2022 Jan 31;14(3):586. doi: 10.3390/polym14030586.
A blend of low molecular azo glass (AZOPD) and polystyrene (PS) were used for the systematic investigation of photo-induced stretching and recovery of nanoimprinted structures. For this purpose, light and heat was used as recovery stimuli. The AZOPD/PS microstructures, fabricated with thermal nanoimprint lithography (tNIL), comprises three different shapes (circles, crosses and squares) and various concentrations of AZOPD fractions. The results show a concentration-dependent reshaping. Particularly the sample with 43 w-% of the AZOPD fraction have shown the best controllable recovery for the used parameters. A possible explanation for shape recovery might be the stabilizing effect of the PS-matrix.
将低分子偶氮玻璃（AZOPD）和聚苯乙烯（PS）混合，用于系统研究纳米压印结构的光致拉伸和恢复。为此，使用光和热作为恢复刺激。通过热纳米压印光刻（tNIL）制造的AZOPD/PS微结构包括三种不同形状（圆形、十字形和方形）以及不同浓度的AZOPD组分。结果表明存在浓度依赖性的重塑。特别是AZOPD组分含量为43重量%的样品在所使用的参数下显示出最佳的可控恢复。形状恢复的一个可能解释可能是PS基体的稳定作用。
