Behaviour of Impurities during Electron Beam Melting of Copper Technogenic Material.
作者信息
Vutova Katia, Stefanova Vladislava, Vassileva Vania, Kadiyski Milen
机构信息
Institute of Electronics, Bulgarian Academy of Sciences, 1784 Sofia, Bulgaria.
Department of Metallurgy of Non-Ferrous Metals and Semiconductors Technologies, University of Chemical Technology and Metallurgy, 1756 Sofia, Bulgaria.
出版信息
Materials (Basel). 2022 Jan 26;15(3):936. doi: 10.3390/ma15030936.
The current study presents the electron beam melting (EBM) efficiency of copper technogenic material with high impurity content (Se, Te, Pb, Bi, Sn, As, Sb, Zn, Ni, Ag, etc.) by means of thermodynamic analysis and experimental tests. On the basis of the calculated values of Gibbs free energy and the physical state of the impurity (liquid and gaseous), a thermodynamic assessment of the possible chemical interactions occurring in the Cu-CuO-Me system in vacuum in the temperature range 1460-1800 K was made. The impact of the kinetic parameters (temperature and refining time) on the behaviour and the degree of removal of impurities was evaluated. Chemical and metallographic analysis of the obtained ingots is also discussed.
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