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用于太阳能电池应用的簇状硅纳米线的高效光捕获

Highly efficient light trapping of clustered silicon nanowires for solar cell applications.

作者信息

Lan Jun, Liu Junbo, Hu Song, Yang Yong

出版信息

Appl Opt. 2022 Jan 10;61(2):369-374. doi: 10.1364/AO.446163.

Abstract

Due to their excellent photoelectric performance, nanostructures have attracted considerable attention in research to improve the power conversion efficiency of thin-film solar cells (TFSCs). Furthermore, cylindrical silicon nanowires (Cy-SiNWs) are regarded as promising candidates for a new generation of TFSCs. On this basis, many new nanostructures derived from conventional Cy-SiNWs have been studied extensively, but most of these structures require high manufacturing accuracy because of their complex morphology. In this paper, an ingenious design of clustered silicon nanowires (Cl-SiNWs) is introduced, whose cross section is similar to the flower shape and consists of four arcs with the same radius. Hence, it requires lower manufacturing difficulty compared with nanostructures with curvature variation of the cross-section profile (i.e., elliptic shape, crescent shape, etc.). In this study, the optical and electrical characterizations are numerically investigated using the finite-difference time-domain method. The numerical simulation shows that the optimized Cl-SiNWs achieve an optical ultimate efficiency () and circuit current density () of 33.66% and 27.54/, respectively, with an enhancement of 7.3% over conventional Cy-SiNWs. Further, the and improve to 42.20% and 34.53/ by adding the silicon substrate and silver backreflector. More importantly, the of Cl-SiNWs always obtained a higher value than Cy-SiNWs at a recommended diameter range of 360-560 nm. Therefore, the suggested Cl-SiNWs have exhibited tremendous potential for the future development of low-cost and highly efficient solar cells.

摘要

由于其优异的光电性能,纳米结构在提高薄膜太阳能电池(TFSCs)功率转换效率的研究中引起了广泛关注。此外,圆柱形硅纳米线(Cy-SiNWs)被认为是新一代TFSCs的有前途的候选材料。在此基础上,许多源自传统Cy-SiNWs的新型纳米结构得到了广泛研究,但由于其复杂的形态,这些结构大多需要高精度制造。本文介绍了一种巧妙设计的簇状硅纳米线(Cl-SiNWs),其横截面类似于花形,由四个半径相同的弧组成。因此,与具有横截面轮廓曲率变化的纳米结构(即椭圆形、月牙形等)相比,它的制造难度更低。在本研究中,使用有限时域差分法对其光学和电学特性进行了数值研究。数值模拟表明,优化后的Cl-SiNWs的光学极限效率()和电路电流密度()分别达到33.66%和27.54/,比传统Cy-SiNWs提高了7.3%。此外,通过添加硅衬底和银背反射器,和分别提高到42.20%和34.53/。更重要的是,在360-560nm的推荐直径范围内,Cl-SiNWs的总是比Cy-SiNWs获得更高的值。因此,所建议的Cl-SiNWs在低成本、高效太阳能电池的未来发展中展现出了巨大潜力。

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