Terenti Natalia, Giurgi Gavril-Ionel, Szolga Lorant, Stroia Ioan, Terec Anamaria, Grosu Ion, Crișan Andreea Petronela
Department of Chemistry and SOOMCC, Faculty of Chemistry and Chemical Engineering, Babeș-Bolyai University, Cluj-Napoca, 11 Arany Janos Str., 400028 Cluj-Napoca, Romania.
Optoelectronics Group, Base of Electronics Department, ETTI, Technical University of Cluj-Napoca, 28 Memorandumului Str., 400114 Cluj-Napoca, Romania.
Molecules. 2022 Feb 11;27(4):1229. doi: 10.3390/molecules27041229.
Four acceptor-donor-acceptor (A-D-A)-type molecules bearing indacenodithiophene as donating central core and various end-capping acceptor units have been designed and synthesised as -type materials suitable for organic solar cells (OSCs). The studied optical and electrochemical properties supported by theoretical calculations revealed that the nature and the strength of the terminal groups exert a decisive influence on the polymer bulk-heterojunction OSC performance.
设计并合成了四种以茚并二噻吩作为供体中心核以及各种端基封端受体单元的受体-供体-受体(A-D-A)型分子,作为适用于有机太阳能电池(OSC)的n型材料。理论计算支持下所研究的光学和电化学性质表明,端基的性质和强度对聚合物本体异质结OSC性能具有决定性影响。