Cobalt Metal-Organic Frameworks with Aggregation-Induced Emission Characteristics for Fluorometric/Colorimetric Dual Channel Detection of Nitrogen-Rich Heterocyclic Compounds.

Nitrogen-rich heterocyclic compounds (NRHCs) are an emerging type of explosive, and their quantification is important in national security inspection and environmental monitoring. Up until now, designing an efficient NRHCs sensing strategy was still in the early stages. Herein, a new metal-organic framework (MOF) with aggregation-induced emission (AIE) characteristics is synthesized with fluorometric/colorimetric responses for rapid and selective detection of NRHCs. The nonemissive probe is designed with tetraphenylethylene derivative as the linker and Co as the node, quencher, and color-changing agent. Cobalt AIE-MOF exhibits a turn-on emission enhancement due to the competitive coordination substitution between NRHCs and the scaffold as well as the following AIE process of the liberative linkers. Meanwhile, the color appearance of the probe changes from blue to yellow based on the dissociation of the original Co coordinating system. Using this dual-mode probe, single- and dual-ring NRHCs are successfully detected from 5 μM to 7.5 mM within 25 s. The cobalt AIE-MOF exhibits excellent selectivity of NRHCs against a variety of interferences, providing a promising tool for designing a multichannel detection strategy.