基于聚（N-乙烯基吡咯烷酮）和可逆加成-断裂链转移（RAFT）聚合技术的复杂大分子结构合成的最新进展
Recent Advances in the Synthesis of Complex Macromolecular Architectures Based on Poly(N-vinyl pyrrolidone) and the RAFT Polymerization Technique.
作者信息
Roka Nikoletta, Kokkorogianni Olga, Kontoes-Georgoudakis Philippos, Choinopoulos Ioannis, Pitsikalis Marinos
机构信息
Industrial Chemistry Laboratory, Department of Chemistry, National and Kapodistrian University of Athens, Panepistimiopolis Zografou, 15771 Athens, Greece.
出版信息
Polymers (Basel). 2022 Feb 11;14(4):701. doi: 10.3390/polym14040701.
Recent advances in the controlled RAFT polymerization of complex macromolecular architectures based on poly(N-vinyl pyrrolidone), PNVP, are summarized in this review article. Special interest is given to the synthesis of statistical copolymers, block copolymers, and star polymers and copolymers, along with graft copolymers and more complex architectures. In all cases, PNVP is produced via RAFT techniques, whereas other polymerization methods can be employed in combination with RAFT to provide the desired final products. The advantages and limitations of the synthetic methodologies are discussed in detail.
本文综述了基于聚（N-乙烯基吡咯烷酮）（PNVP）的复杂大分子结构的可控RAFT聚合的最新进展。特别关注了无规共聚物、嵌段共聚物、星形聚合物和共聚物以及接枝共聚物和更复杂结构的合成。在所有情况下，PNVP都是通过RAFT技术制备的，而其他聚合方法可以与RAFT结合使用以提供所需的最终产物。详细讨论了合成方法的优点和局限性。
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