Faculty of Chemistry and Chemical Technology, University of Ljubljana, Mirce 21, Ajdovščina, Ljubljana, Slovenia.
Chair of Materials and Polymer Engineering, Center Odličnosti za Biosenzoriko, Instrumentacijo in Procesno kontrolo, Ajdovščina, Slovenia.
J Sep Sci. 2022 Jun;45(12):1984-1996. doi: 10.1002/jssc.202100955. Epub 2022 Mar 7.
Modern convection-based supports differ substantially in pore size, porosity, and microstructure topology. Due to such variability, it is challenging to evaluate the contribution of a particular microstructure topology on flow resistance. We demonstrated that the flow resistance parameter ( ) introduced decades ago can be used as a criterion to evaluate the effect of microstructure topology on a pressure drop when the pore size is used as a characteristic support dimension. Furthermore, the value of simple cubic packing was calculated over the entire range of open porosity and compared to the values determined for pressure drop models derived for particular convection-based supports and experimental values of various convection-based supports from the literature. It was shown that different convection-based supports become clustered into distinct groups when plotted according to their and open porosity values, allowing their discrimination.
现代基于对流的支撑物在孔径、孔隙率和微观结构拓扑方面有很大的不同。由于这种可变性,评估特定微观结构拓扑对流动阻力的贡献具有挑战性。我们证明,几十年前引入的流动阻力参数( )可以用作当孔径用作特征支撑尺寸时评估微观结构拓扑对压降影响的标准。此外,还计算了简单立方堆积在整个开放孔隙率范围内的 值,并与为特定基于对流的支撑物推导的压降模型的 值以及文献中来自各种基于对流的支撑物的实验值进行了比较。结果表明,当根据它们的 值和开放孔隙率值进行绘制时,不同的基于对流的支撑物会聚类成不同的组,从而可以对它们进行区分。