Synthesis and computational aspects of Al(II)-Al(II) and Ga(II)-Ga(II) dihalides based on an amidinate scaffold.

作者信息

Kumar Arun, Banerjee Samya, Sharma Nishant, Nazish Mohd, Graw Nico, Herbst-Irmer Regine, Stalke Dietmar, Lourderaj Upakarasamy, Roesky Herbert W

机构信息

Institut für Anorganische Chemie, Georg-August-Universität Göttingen, 37077 Göttingen, Germany.

Department of Chemistry, Indian Institute of Technology (BHU), Varanasi, Uttar Pradesh 221005, India.

出版信息

Dalton Trans. 2022 Mar 22;51(12):4898-4902. doi: 10.1039/d2dt00317a.

Amidinate compounds with stabilized aluminium(II) and gallium(II) elements of composition LMX (3 and 4) have been prepared from their LMX (1 and 2) precursor, where M = Al (1 and 4) and Ga (2 and 3); L = PhC(NPrCH) (1 and 4) and PhC(NBu) (2 and 3); and X is I (1 and 4) and Cl (2 and 3) and insights into their bonding are gained. The M-M bond lengths are reported along with the single-crystal X-ray structures of 1-4.