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磁扭丝:超疏水磁性纳米颗粒层对水 - 空气界面的磁致变形

Magneto Twister: Magneto Deformation of the Water-Air Interface by a Superhydrophobic Magnetic Nanoparticle Layer.

作者信息

Gunatilake Udara Bimendra, Morales Rafael, Basabe-Desmonts Lourdes, Benito-Lopez Fernando

机构信息

Microfluidics Cluster UPV/EHU, Analytical Microsystems & Materials for Lab-on-a-Chip (AMMa-LOAC) Group, Analytical Chemistry Department, University of the Basque Country UPV/EHU, Leioa 48940, Spain.

Microfluidics Cluster UPV/EHU, BIOMICs Microfluidics Group, Lascaray Research Center, University of the Basque Country UPV/EHU, Vitoria-Gasteiz 01006, Spain.

出版信息

Langmuir. 2022 Mar 22;38(11):3360-3369. doi: 10.1021/acs.langmuir.1c02925. Epub 2022 Mar 9.

Abstract

Remote manipulation of superhydrophobic surfaces provides fascinating features in water interface-related applications. A superhydrophobic magnetic nanoparticle colloid layer is able to float on the water-air interface and form a stable water-solid-air interface due to its inherent water repulsion, buoyancy, and lateral capillarity properties. Moreover, it easily bends downward under an externally applied gradient magnetic field. Thanks to that, the layer creates a stable twister-like structure with a flipped conical shape, under controlled water levels, behaving as a soft and elastic material that proportionally deforms with the applied magnetic field and then goes back to its initial state in the absence of an external force. When the tip of the twister structure touches the bottom of the water container, it provides a stable magneto movable system, which has many applications in the microfluidic field. We introduce, as a proof-of-principle, three possible implementations of this structure in real scenarios, the cargo and transport of water droplets in aqueous media, the generation of magneto controllable plugs in open surface channels, and the removal of floating microplastics from the air-water interface.

摘要

在与水界面相关的应用中,对超疏水表面进行远程操控具有迷人的特性。超疏水磁性纳米颗粒胶体层由于其固有的拒水、浮力和横向毛细作用特性,能够漂浮在水 - 空气界面上并形成稳定的水 - 固 - 气界面。此外,在外部施加的梯度磁场作用下,它很容易向下弯曲。因此,在受控的水位条件下,该层会形成一个稳定的扭曲状结构,呈翻转的圆锥形,表现得如同一种柔软且有弹性的材料,会随着施加的磁场成比例地变形,然后在没有外力的情况下恢复到初始状态。当扭曲结构的尖端接触到水容器底部时,它会提供一个稳定的磁驱动系统,在微流控领域有许多应用。作为原理验证,我们介绍了这种结构在实际场景中的三种可能应用,即水性介质中水滴的输送和运输、开放表面通道中磁控塞的产生以及从水 - 空气界面去除漂浮微塑料。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a8a5/8945397/e4d973079a83/la1c02925_0002.jpg

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