锰（一氧化碳）配合物与紫外线：低温下区域选择性烯烃硅氢化反应的一种有前景的组合
Mn(CO) and UV light: a promising combination for regioselective alkene hydrosilylation at low temperature.
作者信息
Vivien Anthony, Veyre Laurent, Mirgalet Raphaël, Camp Clément, Thieuleux Chloé
机构信息
Université de Lyon, Institut de Chimie de Lyon, Laboratory of Catalysis, Polymerization, Processes and Materials, CP2M UMR 5128 CNRS-UCB Lyon 1-CPE Lyon, CPE Lyon 43 Bd du 11 Novembre 1918, 69616 Villeurbanne, France.
Elkem Silicones, R&I Chemistry, 9 Rue Specia, 69190 Saint Fons, France.
出版信息
Chem Commun (Camb). 2022 Mar 24;58(25):4091-4094. doi: 10.1039/d2cc00377e.
The low temperature regioselective hydrosilylation of various alkenes with (1,1,1,3,5,5,5-heptamethyltrisiloxane) MDM is described using Mn(CO) under UV irradiation with Mn loadings as low as 1 mol%, in the absence of additives and with excellent selectivity and yields. The generation of a manganese radical allowed the anti-Markovnikov hydrosilylation products to be selectively obtained in yields up to 99%.
描述了在紫外线照射下，使用低至1 mol%的锰负载量的Mn(CO)，在无添加剂的情况下，以(1,1,1,3,5,5,5-七甲基三硅氧烷)MDM对各种烯烃进行低温区域选择性硅氢化反应，具有优异的选择性和产率。锰自由基的生成使得能够选择性地获得高达99%产率的反马氏硅氢化产物。
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