Zhou He-Ye, Chen Chuan-Feng
Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Molecular Recognition and Function, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China.
University of Chinese Academy of Sciences, Beijing 100049, China.
Chem Commun (Camb). 2022 Mar 31;58(27):4356-4359. doi: 10.1039/d2cc00943a.
The exploration of macrocycle-based nonporous adaptive crystals (NACs) for adsorption and separation has been one of the hotspots in supramolecular chemistry and crystal engineering. Herein, we developed calix[3]acridan-based NACs to separate industrially important 4-picoline from its isomer mixtures with over 93.8% purity.
探索基于大环的无孔自适应晶体（NACs）用于吸附和分离一直是超分子化学和晶体工程领域的热点之一。在此，我们开发了基于杯[3]吖啶的NACs，用于从其异构体混合物中分离具有重要工业价值的4-甲基吡啶，纯度超过93.8%。
