Mechanochemical activation and oxidation of U(IV)O.
作者信息
Kravchuk Dmytro V, Forbes Tori Z
机构信息
Department of Chemistry, University of Iowa, Iowa City, Iowa 52242, USA.
出版信息
Chem Commun (Camb). 2022 Apr 5;58(28):4528-4531. doi: 10.1039/d2cc00242f.
PMID:35302570
Abstract
Mechanochemical impact induces oxidation of U(IV)O in presence of alkali metal peroxides LiO and NaO during liquid-assisted grinding, resulting in respective alkali U(VI) triperoxide phases ( Na[UO(O)]·9HO), based on powder X-ray diffraction analysis, solid- and solution-phase vibrational spectroscopy.
摘要
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