Graphene oxide supported Yolk - Shell ZnS/NiS with the adjustable air layer for high performance of electromagnetic wave absorber.

Yolk-shell structure materials with the light weight, excellent impedance matching and electromagnetic wave (EMW) loss ability were widely used in the field of absorbing materials. However, the previous researches on this kind of structure always focused on the comparison between solid structure and empty structure. Different from previous studies, in this paper, the effect of yolk-shell structure with different air layer thickness on EMW absorption was studied for the first time. Graphene oxide (GO) supported yolk-shell ZnS/NiS absorbers with adjustable air layer were prepared by a simple two-step hydrothermal method. Through the equivalence of RLC resonant circuit and the elimination of the influence of polarization relaxation and conduction loss, it was found that yolk-shell structure with different air layer thickness will resonate with EMW of different frequencies, thus increasing the loss capacity of materials to EMW of this frequency. At the same time, Compared with the solid structure, the yolk-shell structure can not only make the material lighter, but also cause multiple reflections and scattering of EMW. Noteworthy, yolk-shell structure composite material exhibits the maximum reflection loss (RL) of -63.0 dB at 4.8 GHz and an effective absorption bandwidth (EAB) of 4.1 GHz at a thickness of 1.6 mm. This research provides an idea and basis for the design of absorbing materials that respond to different frequency EMW.