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用于去除制药废水中有机化合物的核壳型光(电)催化剂的最新进展。

Recent development on core-shell photo(electro)catalysts for elimination of organic compounds from pharmaceutical wastewater.

机构信息

Department of Chemistry, College of Engineering and Technology, SRM Institute of Science and Technology, Kattankulathur, Tamil Nadu, 603203, India.

Department of Earth Resources Engineering, Kyushu University, Fukuoka, 819-0395, Japan.

出版信息

Chemosphere. 2022 Jul;298:134311. doi: 10.1016/j.chemosphere.2022.134311. Epub 2022 Mar 17.

Abstract

Pharmaceutical organics are a vital milestone in contemporary human research since they treat various diseases and improve the quality of human life. However, these organic compounds are considered one of the major environmental hazards after the conception, along with the massive rise in antimicrobial resistance (AMR) in an ecosystem. There are various biological and catalytic technologies existed to eliminate these organics in aqueous system with their limitation. Advanced Oxidation processes (AOPs) are used to decompose these pharmaceutical organic compounds in the wastewater by generating reactive species with high oxidation potential. This review focused various photocatalysts, and photocatalytic oxidation processes, especially core-shell materials for photo (electro)catalytic application in pharmaceutical wastewater decomposition. Moreover, we discussed in details about the design and recent developments of core shell catalysts and comparison for photocatalytic, electrocatalytic and photo electrocatalytic applications in pharmaceutical wastewater treatment. In addition, the mixture of inorganic and organic core-shell materials, and metal-organic framework-based core-shell catalysts discussed in detail for antibiotic degradation.

摘要

制药有机物是当代人类研究的一个重要里程碑,因为它们可以治疗各种疾病并提高人类生活质量。然而,这些有机化合物被认为是继概念之后的主要环境危害之一,同时生态系统中的抗微生物药物耐药性(AMR)也在大规模上升。为了消除水系统中的这些有机物,存在各种生物和催化技术,但它们都存在局限性。高级氧化工艺(AOPs)用于通过生成具有高氧化电势的活性物种来分解废水中的这些制药有机化合物。本综述重点介绍了各种光催化剂和光催化氧化工艺,特别是用于光(电)催化应用的核壳材料,用于制药废水分解。此外,我们详细讨论了核壳催化剂的设计和最新发展,并比较了在制药废水处理中光催化、电催化和光电催化应用的性能。此外,还详细讨论了无机和有机核壳材料的混合物以及基于金属有机骨架的核壳催化剂在抗生素降解方面的应用。

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