Dong Yudong, Pei Lianjun, Fu Jindong, Yang Yalong, Liu Tong, Liang Huihui, Yang Hongjian
School of Chemical Engineering and Technology, Hebei University of Technology, Tianjin 300130, China.
Tianjin Energy Investment Group Co., Ltd., Tianjin 300050, China.
Materials (Basel). 2022 Mar 10;15(6):2035. doi: 10.3390/ma15062035.
In this paper, the traditional, silicate-based Portland cement (PC) was employed as the control to explore the impact of adding varying amounts of metakaolin (MK) on the mechanical properties of cement mortar. In fact, as a mineral admixture, metakaolin (MK) has the ability to significantly improve the early strength and sulfate resistance of cement mortar in traditional, silicate-based Portland cement (PC). In addition to this, the performance of Portland cement mortar is greatly affected by the curing mode. The previous research mainly stays in the intermittent curing and alkaline excitation mode, and there are few studies on the influence of relatively humidity on it. Moreover, the paper investigated the impact of four different curing methods about humidity on the mechanical properties and sulfate resistance. The results show that the best content of metakaolin in Portland cement is 10% (M10), and the best curing method is 95% humidity in the first three days followed by 60% humidity in the later period (3#). Based on previous literature that suggests that adding MK thickens water film layer on the surface of mortar, the mechanism of MK increasing the early strength of cement was analyzed. The compressive strength of the Portland cement containing 10% MK (M10) after 1 day curing is 3.18 times that of pristine PC mortar, and is comparable if PC is cured for three days under the same curing conditions. The traditional PC mortar is highly dependent on the wet curing time, and normally requires a curing time of at least seven days. However, the incorporation of MK can greatly reduce the sensitivity of Portland cement to water; MK cement mortar with only three days wet curing (3#M10) can reach 49.12 MPa after 28 days, which can greatly shorten the otherwise lengthy wet curing time. Lastly, the cement specimens with MK also demonstrated excellent resistance against sulfate corrosion. The work will provide a strong theoretical basis for the early demolding of cement products in construction projects. At the same time, this study can also provide a theoretical reference for the construction of climate drought and saline land areas, which has great reference value.
在本文中,采用传统的硅酸盐基波特兰水泥(PC)作为对照,以探究添加不同量偏高岭土(MK)对水泥砂浆力学性能的影响。事实上,偏高岭土(MK)作为一种矿物掺合料,能够显著提高传统硅酸盐基波特兰水泥(PC)中水泥砂浆的早期强度和抗硫酸盐性能。除此之外,波特兰水泥砂浆的性能受养护方式影响很大。以往的研究主要停留在间歇养护和碱性激发模式,关于相对湿度对其影响的研究较少。此外,本文研究了四种不同湿度养护方法对力学性能和抗硫酸盐性能的影响。结果表明,波特兰水泥中偏高岭土的最佳含量为10%(M10),最佳养护方法是前三天湿度为95%,后期为60%湿度(3#)。基于以往文献表明添加MK会使砂浆表面水膜层变厚,分析了MK提高水泥早期强度的机理。养护1天后,含10%MK(M10)的波特兰水泥的抗压强度是原始PC砂浆的3.18倍,在相同养护条件下,若PC养护三天,二者抗压强度相当。传统PC砂浆高度依赖湿养护时间,通常需要至少七天的养护时间。然而,掺入MK可以大大降低波特兰水泥对水的敏感性;仅经过三天湿养护(3#M10)的MK水泥砂浆在28天后可达到49.12MPa,这可以大大缩短原本漫长的湿养护时间。最后,含MK的水泥试件也表现出优异的抗硫酸盐腐蚀性能。该工作将为建筑工程中水泥制品的早期脱模提供有力的理论依据。同时,本研究也可为气候干旱和盐碱地地区的建设提供理论参考,具有重要的参考价值。