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铜催化碳杂原子交叉偶联反应的最新进展。

Recent Advances in Copper-Catalyzed Carbon Chalcogenides Cross- Coupling Reactions.

机构信息

Department of Chemistry, Government General Degree College at Ranibandh, Bankura, WB-722135, India.

Department of Chemistry, Government General Degree College at Mangalkote, Khudrun, Purba Bardhaman-713132, India.

出版信息

Curr Org Synth. 2023;20(3):267-277. doi: 10.2174/1570179419666220324122735.

Abstract

Cu-catalyzed carbon-heteroatom bond formation is a powerful tool in the field of organic synthesis. In the past two decades, numerous Cu-based catalytic systems are developed in both homogeneous and heterogeneous forms. Important developmentshave been reported on Cubased catalytic systems in the field of C-Chalcogenide cross-coupling in the last few decades. Where homogeneous Cu/L-based catalytic systems are found to perform reactions with high selectivity, heterogeneous supported-Cu and Cu-based nanoparticles are found to perform the reactions under sustainable conditions and high recyclability of catalytic systems. This present overview mainly focuses on the recent advances and applications in this fast-growing research field with an emphasis on copper-catalyzed cross-coupling generations of carbon-chalcogenide (S/Se/Te) bonds.

摘要

铜催化的碳杂原子键形成是有机合成领域的有力工具。在过去的二十年中,已开发出许多均相和多相形式的基于 Cu 的催化体系。在过去几十年中,报道了基于 Cu 的催化体系在 C-硫属元素交叉偶联领域的重要发展。其中,均相 Cu/L 基催化体系被发现具有高选择性地进行反应,而负载型 Cu 和基于 Cu 的纳米粒子则被发现可以在可持续条件下和高催化体系可回收性下进行反应。本综述主要侧重于这个快速发展的研究领域的最新进展和应用,重点是铜催化的碳-硫属元素(S/Se/Te)键的交叉偶联。

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