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气体预磁化增强活性炭对 NO 的吸附。

Enhanced adsorption of NO onto activated carbon by gas pre-magnetization.

机构信息

School of Minerals Processing and Bioengineering, Central South University, Changsha 410083, Hunan, PR China.

出版信息

Sci Total Environ. 2022 Jul 15;830:154712. doi: 10.1016/j.scitotenv.2022.154712. Epub 2022 Mar 22.

Abstract

The NO removal efficiency was relatively low in the traditional activated carbon adsorption process. In this work, a gas pre-magnetization and activated carbon adsorption process was developed to enhance the adsorption of NO onto activated carbon. In this innovative and green process, the mixed gas was magnetized in the external magnetic field and then absorbed by activated carbon. The results indicated that the maximal removal rate of NO could be increased from 75.0% to 89.5%, and the NO adsorption capacity of commercial activated carbon in one hour elevated from 2.28 to 2.60 mg/g when the magnetic induction intensity of external magnetic field increased from 0 T to 2 T. The strengthening mechanism of the gas pre-magnetization was investigated. It was found that magnetic field could elevate the oxidation rate of NO by 11.4% and thus promote the physical adsorption of NO onto activated carbon. External magnetic field could increase the reaction activity of NO and promote the chemical reaction between NO and some functional groups (CO, CO and COOH) on the activated carbon and thus promote the chemisorption process of NO.

摘要

传统的活性炭吸附法对 NO 的去除效率相对较低。在这项工作中,开发了一种气体预磁化和活性炭吸附工艺,以增强活性炭对 NO 的吸附。在这个创新和绿色的过程中,混合气体在外磁场中被磁化,然后被活性炭吸附。结果表明,当外磁场磁感应强度从 0 T 增加到 2 T 时,NO 的最大去除率可以从 75.0%提高到 89.5%,商业活性炭在一小时内的 NO 吸附量从 2.28 毫克/克提高到 2.60 毫克/克。研究了气体预磁化的强化机制。结果发现,磁场可以将 NO 的氧化速率提高 11.4%,从而促进 NO 物理吸附到活性炭上。外磁场可以提高 NO 的反应活性,促进 NO 与活性炭上某些官能团(CO、CO 和 COOH)之间的化学反应,从而促进 NO 的化学吸附过程。

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