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污水污泥、土壤和沉积物中的直链烷基苯磺酸盐(LAS):分析测定及环境安全考量

Linear alkylbenzene sulfonates (LAS) in sewage sludges, soils and sediments: analytical determination and environmental safety considerations.

作者信息

De Henau H, Mathijs E, Hopping W D

出版信息

Int J Environ Anal Chem. 1986;26(3-4):279-93. doi: 10.1080/03067318608077120.

DOI:10.1080/03067318608077120
PMID:3533808
Abstract

Linear Alkylbenzenesulphonates (LAS), a major anionic surfactant used in laundry products, can be measured specifically in the environment by instrumental analysis. In addition to a desulphonation-gas chromatography approach, a method based on high performance liquid chromatography has been developed. The main features of the methods are outlined, and LAS concentrations measured in sewage sludge, sediments and sludge amended soils are reported. Knowledge of usage volumes, sewage treatment practices and environmental transport and transformation mechanisms has been used to predict concentrations of LAS. These calculated concentrations were found to agree well with those actually measured in the environment. Both measured and calculated ambient concentrations of LAS are below those which could produce potentially adverse effects in representative surface water, benthic and terrestrial organisms.

摘要

直链烷基苯磺酸盐(LAS)是洗衣产品中使用的一种主要阴离子表面活性剂,可通过仪器分析在环境中进行特定测量。除了脱磺化-气相色谱法外,还开发了一种基于高效液相色谱的方法。概述了这些方法的主要特点,并报告了在污水污泥、沉积物和污泥改良土壤中测得的LAS浓度。利用使用量、污水处理实践以及环境迁移和转化机制的知识来预测LAS的浓度。发现这些计算出的浓度与在环境中实际测得的浓度非常吻合。LAS的实测和计算环境浓度均低于可能对代表性地表水、底栖生物和陆地生物产生潜在不利影响的浓度。

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1
Linear alkylbenzene sulfonates (LAS) in sewage sludges, soils and sediments: analytical determination and environmental safety considerations.污水污泥、土壤和沉积物中的直链烷基苯磺酸盐(LAS):分析测定及环境安全考量
Int J Environ Anal Chem. 1986;26(3-4):279-93. doi: 10.1080/03067318608077120.
2
European risk assessment of LAS in agricultural soil revisited: species sensitivity distribution and risk estimates.重新审视欧洲对农业土壤中LAS的风险评估:物种敏感性分布与风险估计
Chemosphere. 2007 Oct;69(6):880-92. doi: 10.1016/j.chemosphere.2007.07.029. Epub 2007 Aug 31.
3
Development of an analytical procedure to study linear alkylbenzenesulphonate (LAS) degradation in sewage sludge-amended soils.开发一种分析程序以研究污水污泥改良土壤中直链烷基苯磺酸盐(LAS)的降解情况。
J Chromatogr A. 1993 Dec 24;657(1):25-31. doi: 10.1016/0021-9673(93)83031-M.
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Probabilistic risk assessment for linear alkylbenzene sulfonate (LAS) in sewage sludge used on agricultural soil.农业土壤中使用的污水污泥中直链烷基苯磺酸盐(LAS)的概率风险评估。
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New rapid methods for determination of total LAS in sewage sludge by high performance liquid chromatography (HPLC) and capillary electrophoresis (CE).通过高效液相色谱法(HPLC)和毛细管电泳法(CE)测定污水污泥中总直链烷基苯磺酸盐(LAS)的新快速方法。
Anal Chim Acta. 2009 Feb 23;634(2):267-71. doi: 10.1016/j.aca.2008.12.037. Epub 2008 Dec 27.
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Effect of linear alkylbenzene sulphonates (LAS) on the anaerobic digestion of sewage sludge.直链烷基苯磺酸盐(LAS)对污水污泥厌氧消化的影响。
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Sense or no-sense of the sum parameter for water soluble "adsorbable organic halogens" (AOX) and "absorbed organic halogens" (AOX-S18) for the assessment of organohalogens in sludges and sediments.用于评估污泥和沉积物中有机卤素的水溶性“可吸附有机卤素”(AOX)和“吸收有机卤素”(AOX-S18)总和参数的意义与否。
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Fate and effects of linear alkylbenzene sulphonates (LAS) in the terrestrial environment.直链烷基苯磺酸盐(LAS)在陆地环境中的归宿与影响。
Sci Total Environ. 1999 Feb 9;226(2-3):93-111. doi: 10.1016/s0048-9697(98)00395-7.
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Effect of sewage sludges contaminated with polybrominated diphenylethers on agricultural soils.受多溴二苯醚污染的污水污泥对农业土壤的影响。
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Effect of temperature and organic nutrients on the biodegradation of linear alkylbenzene sulfonate (LAS) during the composting of anaerobically digested sludge from a wastewater treatment plant.温度和有机养分对污水处理厂厌氧消化污泥堆肥过程中直链烷基苯磺酸盐(LAS)生物降解的影响
Waste Manag. 2006;26(11):1237-45. doi: 10.1016/j.wasman.2005.09.016. Epub 2005 Nov 18.