Department of Chemistry, Faculty of Science, Shahr-e-Qods Branch, Islamic Azad University, Tehran, Iran.
Department of Chemistry, Faculty of Science, Shahr-e-Qods Branch, Islamic Azad University, Tehran, Iran.
Chemosphere. 2022 Jul;299:134435. doi: 10.1016/j.chemosphere.2022.134435. Epub 2022 Mar 28.
Due to the scarcity of water and the growing industrialization, pharmaceutical wastewater treatment is of particular importance. For this reason, it is necessary to achieve an efficient method to eliminate all types of pharmaceutical pollutants. Herein, synthetic nano-composite is proposed to take a step towards improving the operation of removing pharmaceutical contaminants from the environment and aquatic and industrial effluents. Binary (maltodextrin/reconstituted graphene nanocomposite) and ternary (maltodextrin/reconstituted graphene nanocomposite/copper oxide) nanocomposites were prepared and characterized using, FT-IR, FESEM-EDS, TEM, DLS, and XRD. The nanocomposites were used to eliminate diclofenac and amoxicillin as Pharmaceuticals. The removal of amoxicillin at a concentration of 30 mg/L with an adsorbent dose of 0.05 g and a pH of 7.4 and an optimal temperature of 20 °C in 10 min has the highest removal rate of 86%. In addition, diclofenac with nano-adsorbents prepared under optimal conditions, including an initial concentration of 20 mg/L, adsorbent dose of 0.05 g, adsorption time of 7 min, a temperature of 20 °C and a pH of 7, has the highest removal efficiency of 94%. The results indicated that the prepared nanocomposites are alternative adsorbents to remove Pharmaceuticals from water.
由于水资源的稀缺和工业化的不断发展,药物废水处理显得尤为重要。出于这个原因,有必要开发一种有效的方法来消除所有类型的药物污染物。在这里,合成纳米复合材料被提出来,以改善从环境和水工业废水中去除药物污染物的操作。使用 FT-IR、FESEM-EDS、TEM、DLS 和 XRD 对二元(麦芽糊精/重组石墨烯纳米复合材料)和三元(麦芽糊精/重组石墨烯纳米复合材料/氧化铜)纳米复合材料进行了制备和表征。纳米复合材料被用于去除双氯芬酸和阿莫西林等药物。在 30mg/L 的阿莫西林浓度下,在 0.05g 的吸附剂剂量、pH 值为 7.4 和 20°C 的最佳温度下,10 分钟内的去除率最高,达到 86%。此外,在最佳条件下用纳米吸附剂处理的二氯芬酸,包括初始浓度为 20mg/L、吸附剂剂量为 0.05g、吸附时间为 7min、温度为 20°C 和 pH 值为 7,具有最高的去除效率为 94%。结果表明,所制备的纳米复合材料是从水中去除药物的替代吸附剂。