Department of Physics, Acharya Nagarjuna University, Nagarjuna Nagar, Guntur, 522 510, Andhra Pradesh, India.
Department of Physics, Acharya Nagarjuna University, Nagarjuna Nagar, Guntur, 522 510, Andhra Pradesh, India; Department of Physics, Bapatla Engineering College, Bapatla, 522 102, Andhra Pradesh, India.
Chemosphere. 2022 Jul;299:134477. doi: 10.1016/j.chemosphere.2022.134477. Epub 2022 Mar 31.
The development of excellent photocatalysts is of great significance for the efficient photocatalytic degradation process, however, the low carrier separation efficiency and poor light absorption ability typically limit the performance of photocatalysts. Herein, a visible light responsive heterostructure composed with indium vanadium oxide nanosheets supported bismuth tungsten oxide nanoflakes (InVO/BiWO) was synthetized through in-situ hydrothermal method. Further, the photocatalytic activity was performed for tetracycline (TC) under visible light illumination. The InVO/BiWO heterostructure builds a strong interface between InVO and BiWO to hinder reunion of photoinduced charge carriers, and provides the sensitive agents for the removal of TC. In particular, the InVO/BiWO photocatalyst prepared by taking 5.0 mg of BiWO shows the highest degradation of TC about 97.42% in 72 min. The quenching experiments identified that hydroxyl radicals, and holes dominated in the photocatalytic process. Furthermore, the optimized nanocomposite is stable even after four cycles, which exposes the excellent photostability and reusability of the photocatalyst. In addition, a plausible degradation pathway and mechanism of TC over InVO/BiWO nanocomposite is also projected.
开发优秀的光催化剂对于高效的光催化降解过程具有重要意义,然而,低的载流子分离效率和较差的光吸收能力通常限制了光催化剂的性能。在此,通过原位水热法合成了一种由氧化铟钒纳米片负载氧化钨酸铋纳米片组成的可见光响应异质结构(InVO/BiWO)。进一步,在可见光照射下,对四环素(TC)进行了光催化活性测试。InVO/BiWO 异质结构在 InVO 和 BiWO 之间建立了强界面,以阻止光生载流子的团聚,并为 TC 的去除提供了敏化剂。特别是,当 BiWO 的用量为 5.0mg 时制备的 InVO/BiWO 光催化剂在 72min 内对 TC 的降解率最高可达 97.42%。猝灭实验表明,在光催化过程中起主导作用的是羟基自由基和空穴。此外,即使经过四个循环,优化后的纳米复合材料也很稳定,这暴露了光催化剂的优异的稳定性和可重复使用性。此外,还预测了 TC 在 InVO/BiWO 纳米复合材料上的可能降解途径和机制。