Author affiliations: Department of Physics, University of Illinois at Urbana-Champaign, Urbana, IL 61801.
Materials Research Laboratory, University of Illinois at Urbana-Champaign, Urbana, IL 61801.
Proc Natl Acad Sci U S A. 2022 Apr 12;119(15):e2119429119. doi: 10.1073/pnas.2119429119. Epub 2022 Apr 4.
Charge density waves (CDWs) have been observed in nearly all families of copper-oxide superconductors. But the behavior of these phases across different families has been perplexing. In La-based cuprates, the CDW wavevector is an increasing function of doping, exhibiting the so-called Yamada behavior, while in Y- and Bi-based materials the behavior is the opposite. Here, we report a combined resonant soft X-ray scattering (RSXS) and neutron scattering study of charge and spin density waves in isotopically enriched La1.8−xEu0.2SrxCuO4 over a range of doping 0.07≤x≤0.20. We find that the CDW amplitude is temperature independent and develops well above experimentally accessible temperatures. Further, the CDW wavevector shows a nonmonotonic temperature dependence, exhibiting Yamada behavior at low temperature with a sudden change occurring near the spin ordering temperature. We describe these observations using a Landau–Ginzburg theory for an incommensurate CDW in a metallic system with a finite charge compressibility and spin-CDW coupling. Extrapolating to high temperature, where the CDW amplitude is small and spin order is absent, our analysis predicts a decreasing wavevector with doping, similar to Y and Bi cuprates. Our study suggests that CDW order in all families of cuprates forms by a common mechanism.
电荷密度波 (CDW) 在几乎所有的铜氧化物超导体家族中都有被观察到。但是,这些相在不同家族中的表现一直令人困惑。在基于镧的铜酸盐中,CDW 波矢是掺杂的递增函数,表现出所谓的 Yamada 行为,而在 Y 和 Bi 基材料中则相反。在这里,我们报告了对同位素富集的 La1.8−xEu0.2SrxCuO4 中电荷和自旋密度波的共振软 X 射线散射 (RSXS) 和中子散射的联合研究,掺杂范围为 0.07≤x≤0.20。我们发现 CDW 幅度与温度无关,并在实验可达到的温度以上很好地发展。此外,CDW 波矢表现出非单调的温度依赖性,在低温下表现出 Yamada 行为,在自旋有序温度附近发生突然变化。我们使用 Landau–Ginzburg 理论来描述这些观察结果,该理论适用于具有有限电荷压缩性和自旋-CDW 耦合的金属系统中的非共调 CDW。外推到高温,CDW 幅度较小且没有自旋有序,我们的分析预测掺杂时波矢会减小,类似于 Y 和 Bi 铜酸盐。我们的研究表明,所有铜氧化物家族中的 CDW 有序都通过共同的机制形成。