Effect of Adding Pyrolysis Carbon Black (CBp) on Soft Friction and Metal Wear during Mixing.

In the cracking process of waste tires, pyrolysis carbon black (CBp), as a solid product, accounts for about 35% of the total tire rubber content. Here, the treated CBp has been gradually applied to the tire formula to improve the recycling efficiency of waste tires. This study elucidated the influence of adding CBp during the tire mixing process on soft friction and metal wear. Compared with industrial carbon black (I-CB), the friction coefficient of CBp was smaller at different mixing stages, and the ripple caused by adhesion friction was not evident. After the modified CBp (M-CBp) was obtained by implementing the surface activation of common CBp (C-CBp), the friction coefficient between M-CBp and metal increased by 10%, while the filler dispersion and comprehensive mechanical properties showed an upward trend. The wear rate of metal was higher than that observed after adding I-CB during the same mixing mode; thus, it was necessary to strengthen the wear resistance of the inner-wall surface of the mixing chamber. The -OH group on the M-CBp surface can also participate in the silane coupling reaction and aggravate the metal wear of the mixer chamber wall. Through a comparison of results, the mixing friction coefficient can reflect the strength of filler-rubber interaction, which in turn can preliminarily represent the dispersion effect and comprehensive properties, reveal the reason behind the poor performance of CBp, and highlight the need for modification from the perspective of tribology.