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简便制备具有优异选择性和耐溶剂性的疏松型P84共聚酰亚胺/氧化石墨烯复合膜

Facile Preparation of Loose P84 Copolyimide/GO Composite Membrane with Excellent Selectivity and Solvent Resistance.

作者信息

Han Runlin, Wu Kui, Xu Lingfeng

机构信息

School of Chemistry and Chemical Engineering, Jinggangshan University, Ji'an 343009, China.

出版信息

Polymers (Basel). 2022 Mar 27;14(7):1353. doi: 10.3390/polym14071353.

Abstract

In this study, multilayer graphene oxide (GO) was used to prepare the functional layer of polyimide/GO composite membrane with polyimide (P84) used as the supporting layer. Chitosan added in the functional layer was utilized to adjust the selectivity of the composite membrane. The effects of GO and chitosan contents on membrane morphology and separation performance were investigated in detail. The composite membrane showed high rejection to Congo red and Methyl orange with high flux but low rejection to NaSO and MgCl at 0.2 MPa and ambient temperature. The membrane exhibited excellent solvent resistance in ,-dimethylacetamide (DMAc) after being crosslinked with 0.5 wt.% triethylene tetramine. The result means that a highly selective and solvent-resistant P84/GO composite membrane was prepared with the facile filtration preparation method.

摘要

在本研究中,多层氧化石墨烯(GO)被用于制备以聚酰亚胺(P84)为支撑层的聚酰亚胺/GO复合膜功能层。添加在功能层中的壳聚糖用于调节复合膜的选择性。详细研究了GO和壳聚糖含量对膜形态和分离性能的影响。在0.2MPa和环境温度下,复合膜对刚果红和甲基橙具有高截留率且通量高,但对NaSO和MgCl的截留率低。与0.5wt.%三亚乙基四胺交联后,该膜在N,N-二甲基乙酰胺(DMAc)中表现出优异的耐溶剂性。结果表明,采用简便的过滤制备方法制备了具有高选择性和耐溶剂性的P84/GO复合膜。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0476/9002502/b0bbcee08c89/polymers-14-01353-g001.jpg

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