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作为用于测量人工光源的一维紫外线辐射剂量计的NBT-普朗尼克F-127凝胶的研究。

Study of NBT-Pluronic F-127 Gels as 1D UV Radiation Dosimeters for Measurement of Artificial Light Sources.

作者信息

Sąsiadek-Andrzejczak Elżbieta, Mądrakowska Agata, Kozicki Marek

机构信息

Department of Mechanical Engineering, Informatics and Chemistry of Polymer Materials, Lodz University of Technology, Żeromskiego 116, 90-543 Lodz, Poland.

出版信息

Materials (Basel). 2022 Mar 23;15(7):2370. doi: 10.3390/ma15072370.

Abstract

This work reports on radiochromic dosimeters for 1D UV light measurements. The dosimeter is composed of a 25% Pluronic F-127 that forms a physical gel matrix and nitro blue tetrazolium chloride (NBT) as a radiation-sensitive compound. This dosimeter was exposed to UVA, UVB and UVC radiation, and the radiochromic reactions were followed with reflectance spectrophotometry including changes in light reflectance and color coordinates in the CIELAB color system. The exposition of dosimeters to all UV radiation caused color changes from pale yellow to dark violet, and its intensity increased with increasing absorbed dose. The effects of NBT concentration and UV radiation type on the dose-response of the dosimeters were also examined. The results obtained reveal that the dosimeters are the least sensitive to irradiation with UVC and the most sensitive to irradiation with UVB (e.g., dosimeter with 2 g/dm of NBT was characterized by the following parameters: the threshold dose 0.1 J/cm; the dose sensitivity -5.97 ± 0.69 cm/J; the linear dose range 0.1-2.5 J/cm; the dynamic dose range was equal to 0.1-3 J/cm). The results obtained reveal that the NBT-Pluronic F-127 dosimeters can be potentially useful as 1D sensors for artificial UV radiation sources measurements.

摘要

这项工作报道了用于一维紫外光测量的放射变色剂量计。该剂量计由形成物理凝胶基质的25%普朗尼克F-127和作为辐射敏感化合物的氯化硝基四氮唑蓝(NBT)组成。将此剂量计暴露于UVA、UVB和UVC辐射下,并用反射分光光度法跟踪放射变色反应,包括CIELAB颜色系统中光反射率和颜色坐标的变化。剂量计暴露于所有紫外辐射下都会导致颜色从浅黄色变为深紫色,且其强度随吸收剂量的增加而增加。还研究了NBT浓度和紫外辐射类型对剂量计剂量响应的影响。所得结果表明,该剂量计对UVC照射最不敏感,对UVB照射最敏感(例如,含2 g/dm NBT的剂量计具有以下参数:阈值剂量0.1 J/cm;剂量灵敏度-5.97±0.69 cm/J;线性剂量范围0.1-2.5 J/cm;动态剂量范围等于0.1-3 J/cm)。所得结果表明,NBT-普朗尼克F-127剂量计作为用于人工紫外辐射源测量的一维传感器可能具有潜在用途。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5ada/8999834/aa8c9ece82fd/materials-15-02370-g001.jpg

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