Sąsiadek-Andrzejczak Elżbieta, Kozicki Marek
Department of Mechanical Engineering, Informatics and Chemistry of Polymer Materials, Lodz University of Technology, Żeromskiego 116, 90-543 Lodz, Poland.
Materials (Basel). 2023 Aug 14;16(16):5622. doi: 10.3390/ma16165622.
This work concerns the new idea of textile printing with a multi-color system using pastes containing compounds sensitive to ultraviolet (UV) radiation. A screen printing method based on a modified CMYK color system was applied to a cotton woven fabric. Aqueous printing pastes were prepared from thickening and crosslinking agents and UV-sensitive compounds: leuco crystal violet (LCV), leuco malachite green (LMG), and 2,3,5-triphenyltetrazolium chloride (TTC) instead of the system's standard process colors: cyan, magenta, and yellow. Depending on the number of printed layers and the type of UV radiation (UVA, UVB, and UVC), the modified textile samples change color after irradiation from white to a wide range of colors (from blue, red, and green to purple, brown, and gray). Based on reflectance measurements, the characteristic parameters of the one-, two-, and three-color-printed samples in relation to absorbed dose were determined, e.g., dose sensitivity, linear and dynamic dose response, and threshold dose. This printing method is a new proposal for UV dosimeters and an alternative standard for textile printing. Furthermore, the developed method can be used for the securing, marking, and creative design of textiles and opens up new possibilities for such stimulus-sensitive reactive printing.
这项工作涉及一种采用含紫外线(UV)辐射敏感化合物的浆料的多色系统进行纺织品印花的新想法。一种基于改良CMYK色彩系统的丝网印刷方法被应用于棉织物。水性印花浆料由增稠剂、交联剂和紫外线敏感化合物制备而成:无色结晶紫(LCV)、无色孔雀绿(LMG)和氯化三苯基四氮唑(TTC),而非该系统标准的印刷颜色:青色、品红色和黄色。根据印刷层数和紫外线辐射类型(UVA、UVB和UVC),经改良的纺织品样品在辐照后会从白色变为多种颜色(从蓝色、红色和绿色到紫色、棕色和灰色)。基于反射率测量,确定了单色、双色和三色印刷样品相对于吸收剂量的特征参数,例如剂量敏感性、线性和动态剂量响应以及阈值剂量。这种印刷方法是紫外线剂量计的一项新提议,也是纺织品印花的一种替代标准。此外,所开发的方法可用于纺织品的防伪、标记和创意设计,并为这种刺激敏感型反应印花开辟了新的可能性。